以壳聚糖(CS)为多壁碳纳米管(MWNTs)的分散介质,通过MWNTs/CS膜上大量氨基静电吸附纳米金粒子(nanoAu),使玻碳电极(GCE)表面形成稳定的nanoAu-MWNTs-CS-GCE修饰层,并采用电化学方法初步研究了该修饰电极的性能.探讨了吲哚乙酸(IAA)在该修饰电极上的电化学行为,结果表明,在5~200μmol/L浓度范围内以及0.78V电位条件下,以循环伏安法(CV)测得的氧化峰电流变化值与c(IAA)呈良好的线性关系,其回归方程为,-2.34×10^-4+0.14x,检出限为8.33×10^-6mol/L.相关系数为0.9997.
This study was making use of chitosant as a dispersion medium of multi-walled carbon nanotubes (MWNTs) and formed a stabilizating nanoAu-MWNTs-CS-GCE layer via MWNTs/chitosant with positive charges adsorption of nanoAu with negative charges. Electrochemical method was selected to investigate the performance of the modified electrode and the electrochemical behavior of indole-3-acetic acid. The catalytic current of IAA versus its concentration had a good linearity in a concentration range of 5--200 μmol/L at around -0. 78 V with a detection limit of 8.33× 10-6 mol/L and a correlation coefficient of 0. 9997.