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Recent Developments in Functional Crystals in China
  • 时间:0
  • 分类:O792[理学—晶体学]
  • 作者机构:[1]潍坊学院化学化工与环境工程学院,潍坊261061, [2]山东大学晶体材料国家重点实验室,济南250100
  • 相关基金:国家自然科学基金(51372139); 山东省高等学校科技计划(J14LA52,J15LA09); 山东省自然科学基金(ZR2014JL029,BS2015CL012)
中文摘要:

采用拉曼散射技术研究了立方相KTa0.67Nb0.33O3晶体的系列相变,从声子角度分析了各相变特点。降温过程中立方-四方和四方-正交相变分别发生在-29℃和-95℃左右,正交-三方相变可能发生在-150℃左右。最后简单讨论了晶体的相变机制和居里点与晶体组分的关系,并比较分析了居里点的实验值与理论值的差异。

英文摘要:

A series of phase transitions in cubic KTa0. 67Nb0. 33O3 crystal were researched by Raman scattering technique. Features on each phase transition were analyzed from the perspective of phonons.The cubic-tetragonal and tetragonal-orthorhombic phase transitions appear at about- 29 ℃ and- 95 ℃,respectively,and the orthorhombic-rhombohedral phase transition probably appears at about- 150 ℃ in cooling process. Finally,the phase transition mechanism and the relationship between curie temperature and crystal content were discussed,and the differences between experimental and theory Curie points were compared and analyzed.

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