中文摘要：

以对-二茂铁苯甲酰氯和1，2-二邻-胺基苯氧乙烷为原料，合成了两个新型的含有二茂铁苯基的酰胺化合物，单晶结构显示，二者均为螺旋状分子。化合物3为三斜晶系，P-1空间群，分子中存在两种N-H…O分子内氢键；位于分子端基C46和C8上的氢原子间的达1．62nm，使得分子框架距离达纳米级。化合物4为正交晶系，Pca^2-空间群，分子中也存在N-H…O分子内氢键，并且二茂铁和与之相连的苯环的二面角在3．8°到20．8°之间的变化范围。

英文摘要：

Two new ferrocenylphenyl-containing imides have been synthesized by the reactions of p-ferrocenylbencarboxylchloride with 1,2-di- （o-aminophenoxy） ethane and characterized by X-ray single crystal diffraction. The results show that the compound 3 crystallizes in the triclinic system,space group P -1. The distance between the hydrogen atoms of terminal CA6 and C8 is about 1.62nm. The compound 4 crystallizes in orthorhombic system, space group Pca2 （ 1 ）. Furthermore , there are intramolecular H-bonds in both of the compounds,two kinds of H-bonds in 3 and one kind of H-bond in 4. The dihedral angels of Cp-ring and phenyl ring in both compounds are ranged from 3.8°to 20.8°.