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NaFeTiO4 nanorod/multi-walled carbon nanotubes composite as an anode material for sodium-ion batteries with high performances in both half and full cells
  • 时间:0
  • 分类:TM911[电气工程—电力电子与电力传动] TB332[一般工业技术—材料科学与工程]
  • 作者机构:Key Laboratory of Colloid & Interface Chemistry (Shandong University), Ministry of Education and School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
  • 相关基金:Acknowledgements This research was financially supported by the National Natural Science Foundation of China (No. 21471091), Academy of Sciences large apparatus United Fund (No. 11179043), the Fundamental Research Funds of Shandong University (Nos. 2015JC007 and 2015JC020), and the Taishan Scholar Project of Shandong Province (No. ts201511004).
中文摘要:

高收益的 NaFeTiO 4 nanorods (与在 30-50 nm 的范围和一些的直径直到 1-5 m ) 被一个灵巧的大音阶的第五音胶化方法综合并且第一次为钠离子电池作为阳极材料被利用。获得的 NaFeTiO 4 nanorods 展览 294 妈 的一个高起始的分泌物能力

英文摘要:

NaFeTiO4 nanorods of high yields (with diameters in the range of 30-50 nm and lengths of up to 1-5 μm) were synthesized by a facile sol-gel method and were utilized as an anode material for sodium-ion batteries for the first time. The obtained NaFeTiO4 nanorods exhibit a high initial discharge capacity of 294 mA·h·g^-1 at 0.2 C (1 C = 177 mA·g^-1), and remain at 115 mA·h·g^-1 after 50 cycles. Furthermore, multi-walled carbon nanotubes (MWCNTs) were mechanically milled with the pristine material to obtain NaFeTiO4/MWCNTs. The NaFeTiO4/MWCNTs electrode exhibits a significantly improved electrochemical performance with a stable discharge capacity of 150 mA·h·g^-1 at 0.2 C after 50 cycles, and remains at 125 mA·h·g^-1 at 0.5 C after 420 cycles. The NaFeTiO4/MWCNTs//Na3V2(PO4)3/C full cell was assembled for the first time; it displays a discharge capacity of 70 mA·h·g^-1 after 50 cycles at 0.05 C, indicating its excellent performances. X-ray photoelectron spectroscopy, ex situ X-ray diffraction, and Raman measurements were performed to investigate the initial electrochemical mechanisms of the obtained NaFeTiO4/MWCNTs.

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