从气相氧化、液相氧化和等离子体转化三个方面对分子氧直接氧化甲烷制甲醇的研究进展进行了分析和评述。关于气相和液相转化法,着重介绍了催化剂方面所取得的成果及对反应性能的影响;关于低温等离子体转化法,主要讨论了单一等离子体反应和等离子体催化耦合反应的研究成果。基于分子氧直接氧化甲烷制甲醇的研究现状,提出了今后研究的几个重要方向。
The progresses in three ways for direct oxidation of methane to methanol by molecular oxygen, including gas phase oxidation, liquid phase oxidation and plasma conversion, were reviewed. For the gas phase reaction and liquid phase reaction, the effects of catalyst on the reaction performances of methane to methanol were discussed. For the cold plasma reaction, the research results on single cold plasma reaction and cold plasma-catalytic oxidation reaction were described. Based on the current researches, the future research directions for this reaction was pointed out.