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核壳结构C@MnO2电极材料的制备及其性能研究
  • ISSN号：1002-185X
  • 期刊名称：《稀有金属材料与工程》
  • 时间：0
  • 分类：TQ152[化学工程—电化学工业]
  • 作者机构：景德镇陶瓷学院, 清华大学新型陶瓷与精细工艺国家重点实验室
  • 相关基金：自然科学基金面上项目和创新研究群体项目(51172119,51221291)
作者： 任宪仓, 田传进, 赵禹程, 赵文燕, 汪长安
关键词： 水热法, 核壳结构, 碳球, 二氧化锰, 电极
中文摘要：

以葡萄糖作为碳源,通过一步水热合成法制备出了粒径分布均匀、单分散性良好的胶体碳球。并充分研究了反应时间、反应温度对碳球形貌的影响。随后用胶体碳球和KMnO4通过简单的氧化还原反应,制备出了具有核壳结构的C@MnO2复合微球。对制备出的C@MnO2复合微球进行了循环伏安、恒流充放电、交流阻抗等电化学测试。以葡萄糖为碳源制备出的碳球直径在100200 nm之间,且在对比条件下,当温度为180℃,时间为9 h时,制备出的胶体碳球单分散性好,产率高。通过电化学测试表明复合微球在以1 mol/L Na2SO4为电解液、当电流密度为0.1 A/g时,其比容量为126.3 F/g。

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期刊信息
  • 《稀有金属材料与工程》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国有色金属学会 中国材料研究学会 西北有色金属研究院
  • 主编：张平祥
  • 地址：西安市51号信箱
  • 邮编：710016
  • 邮箱：RMME@c-nin.com
  • 电话：029-86231117
  • 国际标准刊号：ISSN：1002-185X
  • 国内统一刊号：ISSN：61-1154/TG
  • 邮发代号:52-172
  • 获奖情况:
  • 首届国家期刊奖,中国优秀期刊一等奖,中国有色金属工业优秀期刊1等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,美国科学引文索引（扩展库）,英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,中国北大核心期刊（2000版）
  • 被引量:24715