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Graphene-based Li-ion hybrid supercapacitors with ultrahigh performance
  • ISSN号:0567-7351
  • 期刊名称:《化学学报》
  • 时间:0
  • 分类:TM531.4[电气工程—电器] U469.11[机械工程—车辆工程;交通运输工程—载运工具运用工程;交通运输工程—道路与铁道工程]
  • 作者机构:[1]Key Laboratory of Functional Polymer Materials and Centre for Nanoscale Science and Technology, Institute of Polymer Chemistry,College of Chemistry, Nankai University, Tianjin300071, China
  • 相关基金:The authors gratefully acknowledge financial support from Ministry of Science and Technology of the People's Republic of China (MOST) (Grants Nos. 2012CB933401 and 2011DFB50300), and National Natural Science Foundation of China (NSFC) (Grants Nos. 50933003 and 51273093).
中文摘要:

有一个成长要求让混合 supercapacitor 系统克服存在产生的精力密度限制电的双层电容器(EDLC ) ,在力量与最小的牺牲导致下 generation-II supercapacitors 密度和周期生活。这里,一个先进基于 graphene 的混合系统,由插入 graphene 的 Li4Ti5O12 (LTO ) 组成合成阳极(G-LTO ) 和三维的多孔的 graphene 蔗糖阴极,为两个都联合 Li 离子电池(精力来源) 和 supercapacitors (力量来源) 的好处的目的被制作了。基于 Graphene 的材料关于混合 supercapacitor 的高效在两个电极起一个重要作用。例如,与 175 妈的理论能力相比

英文摘要:

There is a growing demand for hybrid supercapacitor systems to overcome the energy density limitation of existing-generation electric double layer capacitors (EDLCs), leading to next generation-Ⅱ supercapacitors with minimum sacrifice in power density and cycle life. Here, an advanced graphene-based hybrid system, consisting of a graphene-inserted Li4Ti5O12 (LTO) composite anode (G-LTO) and a three-dimensional porous graphene-sucrose cathode, has been fabricated for the purpose of combining both the benefits of Li-ion batteries (energy source) and supercapacitors (power source). Graphene-based materials play a vital role in both electrodes in respect of the high performance of the hybrid supercapacitor. For example, compared with the theoretical capacity of 175 mA-h.g-1 for pure LTO, the G-LTO nanocomposite delivered excellent reversible capacities of 207, 190, and 176 mA·1h·g-1 at rates of 0.3, 0.5, and 1 C, respectively, in the potential range 1.0-2.5 V vs. Li/Li+; these are among the highest values for LTO-based nano- composites at the same rates and potential range. Based on this, an optimized hybrid supercapacitor was fabricated following the standard industry procedure; this displayed an ultrahigh energy density of 95 Wh·kg-1 at a rate of 0.4 C (2.5 h) over a wide voltage range (0-3 V), and still retained an energy density of 32 Wh·kg-1 at a high rate of up to 100 C, equivalent to a full discharge in 36 s, which is exceptionally fast for hybrid supercapacitors. The excellent performance of this Li-ion hybrid supercapacitor indicates that graphene-based materials may indeed play a significant role in next-generation supercapacitors with excellent electrochemical performance.

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期刊信息
  • 《化学学报》
  • 北大核心期刊(2014版)
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院上海有机化学研究所
  • 主编:周其林
  • 地址:上海市零陵路345号
  • 邮编:200032
  • 邮箱:hxxb@sioc.ac.cn
  • 电话:021-54925085
  • 国际标准刊号:ISSN:0567-7351
  • 国内统一刊号:ISSN:31-1320/O6
  • 邮发代号:4-209
  • 获奖情况:
  • 首届国家期刊奖,第二届国家期刊奖提名奖,中国期刊方阵“双高期刊”
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:28694