研究了Mn_(1.25)Fe_(0.65)P_(0.5)Si_(0.5-x)B_x(x=0,0.01,0.03,0.04,0.06,0.07)系列化合物的结构及磁性。结果表明,该系列化合物均为Fe2P型六角结构,空间群为P-62m;磁性测量表明该系列化合物都经历了一级相变,并且均存在热滞,但热滞都较小,当硼的原子分数为0.07时,热滞最大值为5K。居里温度随着硼含量的增加,呈现升高的趋势,当硼的原子分数为0.07时,居里温度为325K,而化合物的最大磁熵变呈现下降的规律,当硼的原子分数为0.07时,最大磁熵变为2J/(kg·K)。
The structure and magnetic properties of Mn_(1.25)Fe_(0.65)P_(0.5)Si_(0.5-x)Bx(x= 0,0.01,0.03,0.04,0.06,0.07)compounds were studied.The XRD results show that the main phase of the compounds is Fe_2P-type hexagonal structure with space group P-62 m.Magnetic measurements indicate that the compounds undergo a first-order phase transition,and the thermal hysteresis is very small,the maximum thermal hysteresis is 5Kfor B=0.07(atom fraction).With the increase of the content of B,the Curie temperature increases.When the content of B is 0.07(atom fraction),the Curie temperature is 325 K.and the maximum magnetic entropy is about 2J/(kg·K)for a field change of 1.5T.With the increase of the content of B,the maximum magnetic entropy decreases.