中文摘要：

采用机械活化-高温固相法制备了锂离子电池正极材料LiCo1／3Mn1/3Ni1／3O2，研究了烧结时间与球磨时间对合成产物结构与性能的影响。通过X射线衍射（XRD）、扫描电子显微镜（SEM）和电化学性能测试对所得样品的结构、形貌及电化学性能进行了表征。研究结果表明，优化实验条件下制得的材料具有良好的循环性能，在2．7～4．6V电压范围内，充放电电流值为20mA／g时，初始放电比容量为210．76mAh／g，30次循环后容量保持率为91．98％。

英文摘要：

The LiCo1/3 Mn1/3 Ni1/3O2 cathode materials for lithium-ion batteries were synthesized by mechanical activation-high temperature solid-state method. The effect of reaction conditions （calcination time and ball milling time） on the structure of the products was investigated. The products were analyzed by X-ray diffraction spectroscopy （XRD）, scanning electron microscopy（SEM） and electrochemical tests. The LiCol/s Mnl/s Nil/3 O2 cathode materials prepared under optimized condition have good cyclic performance. The initial discharge capacity is 210. 76mAh/g at a current density of 20mA/g between 2. 7-4. 6V and the discharge capacity retention is 91.98% after 30 cycles.