中文摘要：

通过高酞酸酐与2-氯-5-甲基-1，4-苯醌反应，经过最长线性步骤6步和3步反应，分别以16％和47％的总产率合成了2个1，4-蒽醌衍生物12和14。其中，化合物14的合成为首次报道。所有合成的化合物均采用核磁共振波谱和质谱方法对其进行了表征和确证，并对高酞酸酐与苯醌反应生成1，4-蒽醌的反应机理进行了探讨。

英文摘要：

Using homophthalic anhydride and 2-chloro-5-methyl-1, 4-benzoquinone through the longest linear step 6 steps and 3 steps in the yield of 16% and 47%, and compound 14 is reported for the first time. Their structures are identified by 1H-NMR and MS spectromethodologies. The mechanism of the reaction of homophthalic Anhydride and 1, 4-benzoquinone was discussed.