欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
通过简易的乌尔曼反应,合成出了一系列桥位二级胺基取代的苝二酰亚胺衍生物2a～2d,并对其能级结构进行了表征.紫外-可见光吸收光谱表明,桥位经过二级胺基取代后苝二酰亚胺的带隙变窄,最大吸收峰出现了100 nm以上的红移,从而使吸收范围覆盖到了近红外区.循环伏安测试表明,桥位经过二级胺基取代后的苝二酰亚胺同时呈现出可逆的还原峰和氧化峰,HOMO能级大幅上升,具有双极性半导体特性.初步探讨了桥位吗啡啉基团取代的苝二酰亚胺2d在有机光伏器件中的应用,证明其既可以用作电子受体,也可以用作电子给体.
英文摘要：
A series of perylene diimide derivatives 2a～2d with the substitutions of secondary amino groups at bay positions,were synthesized via simple Ullmann reaction,and their energy levels were charac-terized.From the UV-vis absorption spectra,it was found that,after the introduction of secondary amino into the bay position,the band gaps of perylene diimides became narrower,and the maximum absorption peaks were significantly red-shifted while compared to non-substituted parent compound.Thus,their absorption bands extended to the near-IR range.Through cyclic voltammetry,it was disclosed that 2a,2c,and 2d ex-hibited both reversible reduction and oxidation processes,and their HOMO energy levels increased greatly,indicating bipolar semiconductive characteristics.Preliminary investigation of the application of bis-morpholine substituted perylene diimide 2d in organic photovoltaic devices was performed,and the re-sults demonstrated that 2d could be used as both electron acceptor and electron donor.
同期刊论文项目
同项目期刊论文
Synthesis and photovoltaic properties of perylene diimide derivatives with aryl electron-donating su
Effect of substituents on the aggregate structure and photovoltaic property of violanthrone derivati
Synthesis, characterization, and photovoltaic property of a low band gap polymer alternating dithien
Star-Shaped D-A Small Molecules Based on Diketopyrrolopyrrole and Triphenylamine for Efficient Solut
An ester-functionalized diketopyrrolopyrrole molecule with appropriate energy levels for application
Effect of Solvent-Assisted Nanoscaled Organo-Gels on Morphology and Performance of Organic Solar Cel
Polyisobutenylsuccinimide Derivatives: Synthesis and Their Application in the Dispersing of TiO2 Nan
Effect of end-groups on the photovoltaic property of diphenyl substituted diketopyrrolopyrrole deriv
A green, low-cost, and highly effective strategy to enhance the performance of hybrid solar cells: P
An ester-functionalized diketopyrrolopyrrole molecule with appropriate energy levels for the applica
Performance enhancement of CdS nanorod arrays/P3HT hybrid solar cells via N719 dye interface modific
Assessing the origin of the S-shaped I-V curve in organic solar cells: An improved equivalent circui
Synthesis and Energy Levels of Perylene Diimide Derivatives with the Substitutions of Secondary Amin
A new wide bandgap organic semiconductor and its application in organic UV sensors with tunable resp
Generation of native polythiophene/PCBM composite nanoparticles via the combination of ultrasonic mi
Low-Temperature Solution Processed Utraviolet Photodetector Based on an Ordered TiO2 Nanorod Array-P
A Heterojunction Based on Well-ordered Organic-Inorganic Hybrid Perovskite and Its Photovoltaic Perf
High-Efficiency Polymer Solar Cells Achieved by Doping Plasmonic Metallic Nanoparticles into Dual Ch
High efficient UV-A photodetectors based on monodispersed ligand-capped TiO2 nanocrystals and polyfl
Large-scale fabrication of CdS nanorod arrays on transparent conductive substrates from aqueous solu
Template-free synthesis of vertically aligned CdS nanorods and its application in hybrid solar cells
Incorporation of ester groups into low band-gap diketopyrrolopyrrole containing polymers for solar c
Synthesis and characterization of new electron-withdrawing moiety thieno[2,3-c]pyrrole-4,6-dione-bas
Fine tuning the HOMO energy levels of polythieno[3,4-b]thiophene derivatives by incorporation of thi
期刊信息
位置：