采用鞍点变分方法和鞍点复数转动方法,考虑了相对论修正、质量极化修正等基础上,计算了L"i洞原子"高位三激发态2l2l′nl″2S(m)和2D(m)(m=2—7)高根系列的高精度波函数、相对论能量、精细结构,同时还计算了Auger分宽度和总宽度,通过相对论效应的讨论,对2S(7),2D(6)及2D(7)的组态进行了重新标定.
The relativistic energies and fine structures of the high-lying triply excited states 2l2l′nl″ 2S(m) and 2D(m) (m = 2—7) for the "hollow atom" lithium are studied using the saddle-point variational method and the saddle-point complex-rotation method,including the mass polarization and relativistic corrections. The partial Auger widths and the total widths are also calculated. By the discussion of relativistic effect,we recalibrated the configurations of 2S(7), 2 D(6) and 2 D(7) .