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铅对(Pbx,Sr1—x)0.85Bi0.1TiO3薄膜结构与介电可调性影响的研究
  • ISSN号:1000-324X
  • 期刊名称:《无机材料学报》
  • 时间:0
  • 分类:O484[理学—固体物理;理学—物理]
  • 作者机构:[1]浙江大学硅材料国家重点实验室,杭州310027
  • 相关基金:国家自然科学基金(50372057,50332030);国家重大基础研究计划(973)项目(2002CB613302)
中文摘要:

用溶胶-凝胶法制备了(Pbx,Sr1-x)0.85Bi0.1TiO3薄膜,对其晶相结构、微观形貌和介电可调性进行了研究.结果表明,该薄膜以钙钛矿形式存在.快速热处理过程可分解得到高活性离子,直接形成比相应温度平衡状态析晶时更多的晶相量.这种晶相在一定条件下有分解和再结晶的趋势.随着Pb^2+离子增加和Sr^2+离子减少,钙钛矿相的四方相与立方相间的转变温度升高.薄膜处在铁电相和顺电相转变点附近时,可以获得较大的可调性.

英文摘要:

(Pbx,Sr1-x)0.85Bi0.1TiO3 thin films with perovskite structure were prepared on ITO glass substrate by a sol-gel method. XRD, SEM and impedance analyzer were respectively used to characterize the phase status, morphology and dielectric properties of the films. The results show that during the formation of (Pbx, Sr1-x)0.85Bi0.1TiO3 thin films, nucleus of the perovskite phase are initially formed and then congregated together. These aggregated nucleus are then transformed as the perovskite-phase crystalline. And finally, the crystalline phase grows and separates gradually to form the perfect crystalline structure. The content of the perovskite phase formed in the thin film under rapid thermal process(RTP) is more than that formed in kinetic equilibrium under traditional heat treatment. It is due to the high active decomposed ions forming the perovskite phase directly when heat-treated by RTP. The structure of the perovskite phase has a close relation to the ratio of Pb/Sr in the system because of the difference of radius between Pb^2+ and Sr^2+. The transformation temperature between cubic and tetragonal of the perovskite phase is increased as increasing Pb^2+ whose radius is larger than that of Sr^2+. It appears at room temperature when the content of Pb^2+/Sr^2+ is about 0.4/0.6. Meanwhile, the tetragonality of the perovskite phase is increased with increasing Pb^2+ ions. High tunability of the (Pbx, Sr1-x)0.85Bi0.1TiO3 thin film is exhibited when the film composition is close to transformation point, between paraelectric and ferroelectric. Pb^2+ ions act as a dominant factor to affect the Curie point of the system and then to change tunability.

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期刊信息
  • 《无机材料学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院上海硅酸盐所
  • 主编:郭景坤
  • 地址:上海市定西路1295号
  • 邮编:200050
  • 邮箱:wjclxb@mail.sic.ac.cn
  • 电话:021-52411302
  • 国际标准刊号:ISSN:1000-324X
  • 国内统一刊号:ISSN:31-1363/TQ
  • 邮发代号:4-504
  • 获奖情况:
  • 获"中国百种杰出学术期刊"称号
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  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),瑞典开放获取期刊指南,中国北大核心期刊(2000版)
  • 被引量:21274