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Mn含量对Fe-Mn-Si-Cr-Ni合金记忆效应的影响机制
  • ISSN号:0412-1961
  • 期刊名称:金属学报
  • 时间:2015.2.11
  • 页码:201-208
  • 分类:TG139.6[金属学及工艺—合金;一般工业技术—材料科学与工程;金属学及工艺—金属学]
  • 作者机构:[1]四川大学制造科学与工程学院,成都610065, [2]四川大学分析测试中心,成都610065
  • 相关基金:国家自然科学基金项目51171123和51271128资助
  • 相关项目:退火孪晶界面及其数量对FeMnSi基合金形状记忆效应的影响及控制
中文摘要:

采用OM,EBSD,XRD,TEM和SQUID研究了3种不同Mn含量的固溶态Fe-(14~21)Mn-5.5Si-8.5Cr-5Ni合金在马氏体转变开始温度Ms以上10 K(Ms+10 K)变形前后的形状记忆效应和微观组织.结果表明,固溶态Fe-(14~21)Mn-5.5Si-8.5Cr-5Ni合金的形状记忆效应随Mn含量增加而增加.这是由于:一方面,奥氏体屈服强度与应力诱发e马氏体临界应力的差值随着Mn含量的增加而增大,即提高Mn含量增强了奥氏体抵抗塑性变形的能力;另一方面,Mn含量的提高减小了应力诱发e马氏体的宽度,抑制了a’马氏体的引入,从而提高了应力诱发e马氏体的可逆性.

英文摘要:

Fe-Mn-Si base shape memory alloys(SMAs), as compared with Ni-Ti and Cu base SMAs, have attracted much attention since the 1980 s due to their promising advantages, such as low cost, good workability and weldability. However, the recovery strain of polycrystalline Fe-Mn-Si base SMAs is only about 2%~3% except single crystals and ribbons ones. At the present time, in order to enhance the recovery strain of this kind of alloys,some methods such as thermo-mechanical training, ausforming and thermo-mechanical treatment are used. In recent years, the research group had prepared training-free cast Fe-Mn-Si base alloys showing an excellent shape memory effect(SME). Unfortunately, the grains of cast Fe-Mn-Si base alloys are coarse, certainly leading to low yield strength and recovery stress. Many factors affecting the shape memory effect, such as alloy elements, the amount of pre-strain, deformation temperatures, annealing treatments and the training, have been studied. However, there is a debate on the effect of Mn contents on the shape memory effect of Fe-Mn-Si base alloys. The aim of this work is to clarify the debate, shape memory effect and microstructures of solution treated Fe-(14~21)Mn-5.5Si-8.5Cr-5Ni alloys were investigated by OM, EBSD, XRD, TEM and SQUID before and after deformation at 10 K higher than their start temperature of martensitic transformation(Ms+10 K). The result showed that the shape memory effect of solution treated Fe-(14~21)Mn-5.5Si-8.5Cr-5Ni alloys increased with the Mn contents. There are two reasons for this result. One is that the difference value between austenitic yield strength and critical stress of stressinduced e martensite increased with the Mn contents. In other word, the ability resisting plastic deformation was improved by increasing the Mn contents. The other is that the reversibility of e martensite reverse transformation was enhanced by increasing the Mn contents because the width of stress-induced e martensite decreased while the a’ martensite was diffi

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期刊信息
  • 《金属学报》
  • 中国科技核心期刊
  • 主管单位:中国科学协术协会
  • 主办单位:中国金属学会
  • 主编:柯俊
  • 地址:沈阳文化路72号
  • 邮编:110016
  • 邮箱:shxiao@imr.ac.cn
  • 电话:024-23971286
  • 国际标准刊号:ISSN:0412-1961
  • 国内统一刊号:ISSN:21-1139/TG
  • 邮发代号:2-361
  • 获奖情况:
  • 第一、二届全国优秀科技期刊评比一等奖,第一、二、三届国家期刊奖,国家期刊方阵"双高"期刊,第一、二、三届中国科学院科技期刊评比一等奖,中国科学院优秀期刊特别奖,第一、二、三、五届中国科协优秀科技期刊评比一等奖,中国科协精品期刊工程A类、B类,第一、二、三、四、五届中国百种杰出学术期刊,首届出版政府奖
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  • 被引量:26785