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海水环境中弧菌对45钢腐蚀行为及力学性能的影响
  • ISSN号:1005-4537
  • 期刊名称:中国腐蚀与防护学报
  • 时间:2012.8
  • 页码:343-348
  • 分类:TG172.5[金属学及工艺—金属表面处理;金属学及工艺—金属学]
  • 作者机构:[1]海南优势资源化工材料应用技术教育部重点实验室海南大学材料与化工学院,海口570228
  • 相关基金:国家自然科学基金(50761004和51161007)、海南省自然科学基金(510204和511112)、海南大学2005和2009年科研项目(Kyjj0536和hd09xm77)资助
  • 相关项目:热带海洋气候下海水中微生物协同作用对45钢腐蚀行为的影响
中文摘要:

通过热带海洋气候条件下在海水中培养弧菌,并对比45钢在自然海水、无菌海水和弧菌海水中的腐蚀行为,研究了弧菌对45钢腐蚀行为及力学性能的影响。结果表明,弧菌可以接种于海水中大量培养至高浓度(非培养基中培养),避免了培养基成分的缓蚀作用,从而更接近碳钢的自然腐蚀状态。海水中弧菌对45钢的平均腐蚀速率及力学性能有显著的影响。弧菌能加速45钢的平均腐蚀速率,但微生物的协同作用比单种弧菌更能加速材料的平均腐蚀速率。弧菌能显著降低局部pH值,引起材料表面严重的局部腐蚀,材料表面局部腐蚀促使其在拉伸过程中应力集中而发生断裂。

英文摘要:

It has been found that microbiologically influenced corrosion (MIC) plays a significant role in corrosion process of steels exposed in marine environment. Microbe can produce pitting, crevice corrosion, selective dealloying and stress-oriented hydrogen-induced cracking, which accelerates both localized and average corrosion rates of carbon steel. Wu et al. reported that when the corrosion time is 365 d, the average corrosion depth of 25 steel in natural seawater is 2.6 times higher than that in sterile seawater, and localized attack is also observed on the specimens immersed in natural seawater. Preliminary work also shows that Vibrio is the key component of microbe in the corrosion product. The research on the single effect of Vibrio on the corrosion behaviors and mechanical properties of metal is insufficient up to now. In this work, Vibrio is cultured in seawater. 45 steel coupons are immersed in three different mediums in tropic condition: natural seawater, sterile seawater and Vibrio-containing seawater. The results show that instead of culturing in culture medium, Vibrio can be cultured in seawater to a high concentration, which avoid the corrosion inhibitor behavior from culture medium and near natural corrosion condition. The activity of Vibrio at the interface accelerates the average corrosion rate for 45 steel. Coupons immersed in natural seawater show faster average corrosion rate than in Vibrio-containing seawater due to microbial synergy. Vibrio is acid-producing bacteria which can decrease the local pH value and cause significant local corrosion. Local corrosion in the surface of metal would lead to stress concentration on the local corrosion site and cut down the tensile strength of material.

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期刊信息
  • 《中国腐蚀与防护学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科技协会
  • 主办单位:中国腐蚀与防护学会 中国科学院金属研究所
  • 主编:柯伟
  • 地址:沈阳市文化路72号
  • 邮编:110016
  • 邮箱:jcscp@imr.ac.cn
  • 电话:024-23971819
  • 国际标准刊号:ISSN:1005-4537
  • 国内统一刊号:ISSN:21-1474/TG
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国剑桥科学文摘,英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:7982