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微波接枝CPVC改性秸秆纤维/HDPE复合材料的界面性能
  • ISSN号:1001-9456
  • 期刊名称:《塑料》
  • 时间:0
  • 分类:TQ325.12[化学工程—合成树脂塑料工业]
  • 作者机构:[1]暨南大学化学系,广东广州510632, [2]暨南大学生物医学工程系,广东广州510632
  • 相关基金:国家自然科学基金资助项目(20976068/B060805).
中文摘要:

利用微波接枝CPVC复配偶联荆处理秸秆纤维表面,采用光学法液滴形态分析系统测定处理前后秸秆微粉的动态接触角及表面能变化,并制备相应的复合材料进行力学性能测试。研究结果表明:微波接枝CPVC复配偶联剂界面改性方法对秸秆纤维有较好的改性效果,改性后秸秆纤维的平衡接触角θc由74.65°上升至98,96°,从明显的亲水性转变为疏水性;而表面能则有不同程度减小,改性后秸秆纤维表面能(23.68mJ/m^2)低于HDPE基体(28.61mJ/m^2);经微波接枝CPCC改性后秸秆纤维复合材料保持了良好的力学性能。较透彻地了解秸秆纤维复合材料的复合界面特性及其复合机理,设计和制造不同性能、满足不同应用领域要求的纤维复合材料产品,是秸秆纤维复合材料研究工作者至今仍在继续探索的重要研究领域。

英文摘要:

CPVC double-component blending coupling agents were used to treat the surface of straw fibers by microwave-grafting. The change of dynamic contact angle and surface energy of untreated and treated straw micro powder were measured by optical method ,and relative composite were prepared to carry mechanics properties tests. The experimental results showed that the surface modification using microwave-grafted CPVC double-component blending coupling agents had relative effect on straw fiber. The balance contact angle (θc) of treated straw increased from 74.65° to 98.96°, and the straw was converted from obvious hydrophilic to hydrophobic. The surface energy had some degree of decrease after modification, from 28.61 mJ/m^2 to 23.68 mJ/m^2. The straw composite maintained well mechanics properties after modified by microwave-grafted CPVC. The composite interface characteristics and mechanism of straw composite were studied. In order to meet demands of different application fields ,designing and producing fiber composites with different functions were necessary, and it was an important research field which straw fiber composite researchers continued to explore until now.

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期刊信息
  • 《塑料》
  • 中国科技核心期刊
  • 主管单位:北京隆达轻工控股有限责任公司
  • 主办单位:北京市塑料研究所
  • 主编:杨明锦
  • 地址:北京西城区旧鼓楼大街47号
  • 邮编:100009
  • 邮箱:plastics@163bj.com
  • 电话:010-84022529 84035979
  • 国际标准刊号:ISSN:1001-9456
  • 国内统一刊号:ISSN:11-2205/TQ
  • 邮发代号:82-268
  • 获奖情况:
  • 科技论文统计源期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:9561