利用反应显微成像谱仪,研究了50 keV/u Ne8+碰撞CO转移电离反应中生成的CO2+碎裂过程。通过重构分子离子爆炸碎片C+和O+的三维动量,获得了质心系中CO2+碎裂过程中释放的动能(KER)。在KER谱中发现了来自亚稳态1Σ~+,~1Π,~3Π解离的峰、3Σ~+态解离的峰和1Σ~+(II)态解离的峰,同时发现了排斥态3Σ~-的贡献。在3Σ~-态解离的分子轴取向分布中,首次观测到CO2+解离的分子轴取向效应。
The fragmentations of CO2+ are studied in transfer ionization processes of 50 ke V/u Ne8+ impact on CO with reaction microscopes. The 3D momenta of C+ and O+ were measured, and the kinetic energy release(KER) of dissociative(CO2+) was obtained accordingly. The peaks resulted from the metastable states of 1Σ~+,~1Π and 3Π, of 3Σ~+, and of 1Σ~+(II)are identified in KER spectrum. Meanwhile, the repulsive state of 3Σ~- was also observed, which forms a broad peak lying between the peaks of ~3Σ~+ and 1Σ~+(II). In the CO2+ dissociations from 3Σ~- state, the orientation effect of CO molecular axis was observed for the first time.