中文摘要：

从（1R，2S）-环己烷吡啶醇出发，合成了具有不同轴手性的反式环己烷骨架铱络合物，并将其应用于3-羟甲基-2H-苯并吡喃的不对称氢化中．结果表明，当以Ir-8为催化剂，二氯甲烷为溶剂，氢气压力5MPa，室温反应16h时，可以取得极好的反应活性，产物最高对映选择性可达94％．

英文摘要：

Trans-cyclohexane-backbone iridium complexes with different axial chirality were synthesized from （ 1 R, 2 S ）-2- （pyridin-2-yl） cyclohexanol, and their application in asymmetric hydrogenation of （2 H-chromen-3- yl）methanols was investigated. When the hydrogenation was carried out using 1% It-8 as the catalyst at a hydrogen pressure of 5 MPa in dichloromethane for 16 h at room temperature, excellent activities and up to 94% ee were obtained.