采用MP2/6-31G(D,P)方法对HOOOH的反式和顺式转化机理进行了详细计算研究。计算结果表明:(1)HOOOH的反式比顺式结构稳定;(2)两种稳定构型的异构化反应机理存在两种路径。
The two transition states have been investigated using the MP2 theory between cis-HOOOH and trans-HOOOH, The results shows that: (1) trans-isomers is more stable than cis-isomers; (2) there are two pathways of the conversion between the trans-HOOOH and eis-HOOOH.