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减压浓缩对沼液CO_2吸收性能和植物生理毒性的影响
  • ISSN号:1000-1298
  • 期刊名称:《农业机械学报》
  • 时间:0
  • 分类:S216.4[农业科学—农业机械化工程;农业科学—农业工程]
  • 作者机构:华中农业大学工学院,武汉430070
  • 相关基金:国家自然科学基金项目(51376078); 中央高校基本科研业务费专项(2015PY077)
中文摘要:

利用减压浓缩试验装置在50℃和2 k Pa下对沼液进行浓缩,分别测试了沼液、沼液浓缩相及冷凝回收稀相的CO2吸收性能和植物生理毒性。结果表明,沼液减压浓缩到4倍时,沼液浓缩相p H值升高至8.73,其饱和CO2吸收负荷增加26.70%,氨氮去除率为86.41%。浓缩相中的大部分氨氮以自由氨的形式转移到沼液稀相中,使稀相p H值达到10.05,饱和CO2吸收负荷达0.075 mol/L。但浓缩相和稀相的净CO2吸收容量之和比原沼液降低21.3%,其主要原因在于减压浓缩过程中自由氨的挥发损失。用原沼液、浓缩沼液及稀相的富CO2溶液育种时,大白菜种子的发芽指数(GI)均大于0.8,表现出较低的植物生理毒性,说明减压浓缩可降低消纳沼液所需的农田面积。试验中也对不同类型CO2吸收强化添加剂的性能进行了比较。在相同的CO2吸收强化性能要求下,钠盐添加剂组富CO2沼液的植物生理毒性低于氨水添加剂组,其主要原因在于添加氨水导致了沼液氨氮含量的大幅增加。

英文摘要:

Raw biogas slurry( RBS) was concentrated to obtain the concentrated biogas slurry( CBS)and the diluted phase( DP) condensed by the gas phase under the conditions of 50℃ and 2 k Pa in vacuum concentration device. CO2 absorption performances of RBS,CBS and DP were investigated,and the germination index( GI) values of Chinese cabbage seeds germinated by these solutions after CO2 absorption were evaluated as well. Results showed that when the concentration degree of RBS was about4,the p H value of CBS was increased from 7. 87 to 8. 73,and its saturated CO2 loading was increased by about 26. 70%. Additionally,the removal efficiency of ammonium nitrogen was up to 86. 41% due to the conversion of ammonium nitrogen into free ammonia and then extracted from biogas slurry by vacuum operation. Most of the free ammonia was condensed and collected into the DP. Therefore,DP's p H value and CO2 loading were up to 10. 05 and 0. 075 mol / L,respectively. However,the net CO2 absorption capacity contributed by CBS and DP was 21. 3% lower than that of RBS due to the volatile loss of ammonia during concentration. Results from the germination of Chinese cabbage seeds by the CO2-rich solutions of RBS,CBS and DP showed that all the GI values were higher than 0. 8,implying their low phytotoxicities. The result implied that concentrating RBS may result in the decrease of the cropland area required to dispose the biogas slurry. Moreover, CO2 absorption enhancement by adding different additives was investigated and compared as well. Aiming at the same saturated CO2 loading value,adding sodium salts into biogas slurry was superior to adding ammonia additives in terms of low phytotoxicity,which may be attributed to the great increase of ammonium nitrogen concentration in the latter solutions.

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期刊信息
  • 《农业机械学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国农业机械学会 中国农业机械化科学研究院
  • 主编:任露泉
  • 地址:北京德胜门外北沙滩一号6号信箱
  • 邮编:100083
  • 邮箱:njxb@caams.org.cn
  • 电话:010-64882610 64867367
  • 国际标准刊号:ISSN:1000-1298
  • 国内统一刊号:ISSN:11-1964/S
  • 邮发代号:2-363
  • 获奖情况:
  • 荣获中国科协优秀期刊二等奖,1997~2000年连续4年获中国科协择优资金,被列入中国期刊方阵,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),英国农业与生物科学研究中心文摘,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:42884