全固态锂离子二次电池具有更大能量密度和更高的安全使用性能,在未来的电动汽车和蓄能电站上有很好的应用前景。本文介绍了无机固态锂离子电解质的研究进展,分类讨论了Perovskite型、NASICON型、LISICON型、LiPON型、Li3 PO4-Li4 SiO4型、GARNET型无机固态锂离子电解质的性能、结构和导电机理及其在锂离子二次电池中的应用。
olid state lithium ion batteries have the advantages of high energy capacity and safety.They have potential applications in electric vehicle and energy storage.The research and development of inorganic solid state lithium ion electrolyte were classified and discussed with emphasis on the Perovskite,NASICON,LISICON,LiPON,Li3PO4-Li4SiO4,GARNET type electrolyte.The properties,structural characteristics,conducting mechanism and applications of inorganic solid state lithium ion electrolytes for lithium ion secondary batteries were reviewed.