以2-(3-吡啶)-4,5-咪唑二羧酸(H3PIDC)为配体,采用溶剂热合成方法得到了配合物[Cd(H2PIDC)(H2O)Cl]n(1),用X-射线衍射法测定了配合物的晶体结构.结果表明,配合物1属于三斜晶系,空间群为P-1,2个Cd原子通过2个氯原子桥连成1个四元环,再通过吡啶环上的氮连成1个1维链状结构.并对配合物做了荧光性质研究.
One new complex[Cd(H2PIDC)(H2O)Cl]n(1)[H2PIDC=2-(pyridin-3-yl)-1H-imidazole-4,5-dicarboxylic]has been synthesized through solvothermal synthesis reactions and characterized by elemental analyses and single-crystal X-ray diffraction analyses.Complex 1 shows a one-dimensional chain structure and its fluorescence properties have been studied.