5-羟甲基糠醛(5-HMF)被认为是一种非常重要的平台化合物。利用离子液体介导制备5-HMF的研究已经引起了人们越来越广泛的重视,并取得了较为理想的研究成果。本文对离子液体介导制备5-HMF的研究成果进行了系统的归纳和总结,着重介绍了离子液体作为反应溶剂和催化剂在5-HMF制备过程中的应用以及离子液体介导制备5-HMF的形成机理和影响因素,并对离子液体介导制备5-HMF的研究前景进行了展望,以期为5-HMF的进一步研究提供思路和参考。
5-Hydroxymethylfurfural (5-HMF) is considered as a very important biomass-based platform compound that can be used to synthesize a broad range of liquid fuels and chemicals, which are mainly derived from fossil resources so far. The study of the production of 5-HMF in the presence of ionic liquids has increasingly attracted more attention. In this review, the recent achievements of ionic liquids-mediated formation of 5-HMF are systematically summarized, including applications of ionic liquids as reaction solvents and catalysts in the production of 5-HMF, influence factors and formation mechanisms in the ionic liquids-mediated formation of 5- HMF. The future research trends of ionic liquids-mediated formation of 5-HMF are suggested.