采用电化学、微生物学和表面分析的方法,研究了厌氧环境硫酸盐还原菌(subtere ducing bacteria,SRB)溶液中Al-6Mg-Zr添加Sc元素前后的腐蚀行为。结果表明,添加Sc元素后,合金的氧化膜更加致密,具有更好的保护作用,使电极开路电位正移100mV左右,同时Sc元素的加入降低了材料在SRB菌液中的点蚀敏感性,使材料耐微生物腐蚀性能得到提高,但是添加Sc后的合金对SRB更加敏感。显微观察表明添加Sc前后两种铝镁合金的腐蚀特征均为点蚀,能谱分析表明随浸泡时间增加,腐蚀越来越严重,腐蚀产物堆积和阳极金属溶解造成进一步腐蚀。
The corrosion behaviors of Al-6Mg-Zr and Al-6Mg-Zr-Sc in sulfate-reducing bacteria(SRB) solution in the anaerobic environment were studied by electrochemical, microbiology and surface analysis methods. It is found that the oxide film is more compact resulting in the open circuit potential shifting about 100 mV positively due to the addition of Sc. On the other hand, it is demonstrated that pitting sensitivity of Al-6Mg-Zr-Sc alloy in the SRB solution is decreased and its microbiologically influenced corrosion resistance is improved. But the alloy with Sc addition is sensitive to SRB. The pitting corrosion occurring on both alloys surface under the comprehensive action of the metabolism of SRB is observed by SEM. It is obtained by EDS that the corrosion degree increases with time and the corrosion is furthered by the depositing of product and the dissolution of metals.