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土壤不同有机质组分对菲的吸附特征研究
  • ISSN号:1000-6923
  • 期刊名称:《中国环境科学》
  • 时间:0
  • 分类:X53[环境科学与工程—环境工程]
  • 作者机构:[1]福建师范大学地理科学学院,湿润亚热带生态地理过程教育部重点实验室,福建福州350007
  • 相关基金:基金项目:国家自然科学基金资助项目(40971265)
中文摘要:

采用批次实验,研究了三种不同类型土壤黄红壤、水稻土和草甸土的全土、重组、去松结态和紧结态4个组分对菲的吸附,结果表明.菲在不同土壤及其组分上的吸附等温线都能用Freundlich方程进行拟合,所有等温线都具有一定程度的非线性,指数N值的大小顺序基本都为全土,重组〉去松结态〉紧结态.除了黄红壤的紧结态比去松结态对菲的吸附容量坼值略小外,不同土壤及其组分对菲吸附的KF值以及有机碳归一化的KFOC值大小顺序都为紧结态〉去松结态〉重组〉全土.不同类型土壤之间的群值大小顺序为草甸土〉水稻土〉黄红壤,而KFOC值大小顺为水稻土〉草甸土〉黄红壤.所值与有机碳含量之间呈显著性正相关(P〈0.05),KFOC与N之间呈极显著负相关(P〈0.001).土壤及其组分对菲的吸附强度与有机质的结构特征和聚合程度有关.

英文摘要:

Three fractions of organic matter (heavy fraction (HF), heavy fraction without the loosely combined humus (WLH), and tightly combined humus (TH) were separated from three soil types named yellow-red soil, paddy soil and meadow soil. Batch experiments were conducted to study the sorption of phenanthrene by HF, WLH, TH and bulk soils (BS). Results showed that all sorption isotherms ofphenanthrene by the different organic matter fractions and bulk soils fitted Freundlich equation and were nonlinear in some degree. The values of Freundlich exponent coefficient (N) followed the order of BS 〉 HF 〉 WLH 〉 TH. The sorption capacity (KF) and its organic carbon normalized parameter (KFoc) for phenanthrene were in the order ofTH 〉 WLH 〉 HF 〉 BS, except that KF of TH was less than that of WLH in yellow-red soil. The KF values of different soils were in the order of meadow soil〉paddy soil〉yellow-red soil. However, the KFo~ values were in the order of paddy soil〉meadow soil〉yellow-red soil. The KF values had a significantly positive correlation (P〈0.05) with the organic carbon content of sorbents, and the KFoc values had a very significantly negative correlation (P〈0.001) with the N values. The structural characteristics and degree of polymerization of organic matter were related to the sorption ofphenanthrene in soils.

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期刊信息
  • 《中国环境科学》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国环境科学学会
  • 主编:王文兴
  • 地址:北京市海淀区红联南村54号
  • 邮编:100082
  • 邮箱:zghjkx1981@126.com
  • 电话:010-62215145
  • 国际标准刊号:ISSN:1000-6923
  • 国内统一刊号:ISSN:11-2201/X
  • 邮发代号:2-572
  • 获奖情况:
  • 国家期刊提名奖,国家“双效”期刊,第三届中国科协优秀科技期刊一等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,英国科学文摘数据库,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:47702