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中文摘要：
通过富勒烯C60与肌氨酸和有机醛化合物的1，3-偶极环加成反应，获得了九种含不同有机功能基团的C60吡咯烷衍生物1～9,用^1HNMR，^13CNMR，FTIR，UV—vis和FAB-MS进行了结构表征：利用皮秒激光光源，采用z扫描技术测定了分子的三阶非线性超极化率γ（3），结果显示：化合物3γ（3）=4．14×10^-33 esu）具有最大的三阶非线性光学系数，说明增加噻吩共轭链的长度，使三阶非线性活性增加；对具有相同共轭链的C60-噻吩吡咯烷衍生物（2，5，1和4），吸电子取代基减小了三阶光学非线性活性，给电子基增大了三阶光学非线性活性；同时发现喹啉环2-位键联（7）比4-位（8）有更好的三阶光学非线性活性．
英文摘要：
A series of azomethine ylides were prepared through the reaction between the different substituted conjugated aldehydes and sarcosine. Further 1,3-dipolar cycloaddition of these azomethine ylides to C60 gave a series of new fulleropyrrolidine derivatives 1～9. The molecular structures were identified and characterized by ^1H NMR, ^13C NMR, FTIR, UV-vis and FAB-MS spcctra. The third-order nonlinear optical hyperpolarizabilities γ（3） were obtained under picosecond laser by z-scan technique. It was found that the γ（3） value of 3 （4.14× 10^-33 esu） is the largest which indicates that the γ（3） values become larger with the increasing length of nT. We also found that different substituents at the a position of the thiophene rings （2, 5, 1 and 4）, different position of N atom of quinoline （7 and 8） and different kinds of conjugate chain have different effects on the nonlinear optical properties of fulleropyrrolidine dyads.
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