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具有非穿插α-Po拓扑的Gd-Cu异金属配聚物 [Gd2Cu3 （bpy）2（ip）6]·6H2O
  • ISSN号：0023-074X
  • 期刊名称：《科学通报》
  • 时间：0
  • 分类：O641.4[理学—物理化学;理学—化学] TP393.1[自动化与计算机技术—计算机应用技术;自动化与计算机技术—计算机科学与技术]
  • 作者机构：[1]中国科学院福建物质结构研究所结构化学国家重点实验室,福州350002, [2]河南大学化学化工学院,开封475000, [3]福州大学化学化工学院,福州350002
  • 相关基金：国家杰出青年科学基金（批准号：20725101）、国家重点基础研究发展计划（编号：2006cB932904）、福建省自然科学基金（编号：E0510030,2008F3120）、国家自然科学基金付比准号：50872133,20821061）和中国科学院知识创新工程青年人才领域前沿项目（编号：KJCX2.YW.H01）资助
作者： 贾向丽[1], 周健[1], 赵俊伟[2], 李朝晖[3], 郑寿添[1], 杨国昱[1]
关键词： 水热合成, α-Po拓扑, 异金属配聚物
中文摘要：

水热合成了一个新颖的三维孔状Gd-Cu异金属配聚物[Gd2Cu3（bpy）2（ip）6]？6H2O （1） （bpy = 2,2＇-联吡啶, H2ip = 间苯二酸）, 并对其结构进行了表征. 该化合物属于三斜晶系, 空间群为 , 具有非穿插α-Po拓扑结构及一维孔道, 且六核链状水簇横跨在一维孔道中. 此外, 对该化合物的热稳定性及顺磁光谱进行了测试.

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期刊信息
  • 《科学通报》
  • 北大核心期刊（2011版）
  • 主管单位:中国科学院
  • 主办单位:中国科学院
  • 主编：周光召
  • 地址：北京东黄城根北街16号
  • 邮编：100717
  • 邮箱：csb@scichina.org
  • 电话：010-64036120 64012686
  • 国际标准刊号：ISSN：0023-074X
  • 国内统一刊号：ISSN：11-1784/N
  • 邮发代号:80-213
  • 获奖情况:
  • 首届国家期刊奖,中国期刊方阵“双高”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
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  • 被引量:81792