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中文摘要：
在水热条件下,分别用过渡金属离子Zn（Ⅱ）和Co（Ⅱ）与混合手性羧酸和含氮配体反应,合成了2个手性金属-有机配位聚合物[M（D-cam）（H2mbdpz）]n[M=Zn（1）,Co（2）;D-H2cam=D-（＋）-樟脑酸;H2mbdpz=4,4＇-亚甲基二（3,5-二甲基吡唑）].通过单晶X射线衍射、粉末X射线衍射、元素分析、热重分析及荧光分析对其结构、组成和性质进行了表征.单晶结构分析表明,配合物1和2是异质同晶的手性三维开放骨架结构,具有单节点三连接的ThSi2型网络拓扑结构.
英文摘要：
Two new homochiral metal-organic coordination polymers[M（D-cam）（H2mbdpz）]n[M=Zn（complex 1）,Co（complex 2）;D-H2cam=D-（＋）-camphoric acid,H2mbdpz=4,4′-methylenebis（3,5-dime-thylpyrazole）] were prepared by mixing ligands with corresponding transition metal ions under hydrothermal conditions.The complexes were characterized by means of single-crystal X-ray diffraction,elemental analysis,thermograrimetri analysis（TGA）,powder X-ray diffraction（XRD） and photoluminescent（PL） spectrometry.X-ray crystallography reveals that complexes 1 and 2 are isomorphous and homochiral,exhibiting the three-dimensional open structure with a ThSi2 type of uninodal 3-connected networks.
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