筛选驯化得到具有高效脱硫性能的菌群,在气升式反应器中进行了H2S脱除实验研究.在温度为28℃、初始pH8.0的条件下考察了不同通气量对反应体系中H2S脱除能力、脱除效率的影响以及H2S进气负荷和通气量对SO4^2-生成率的影响.结果表明,最佳通气量为0.2L/min.在此通气量下,当H2S进气负荷为5.76kg·m^-3·d^-1时,脱除负荷可达5.62kg·m^-3·d^-1,而脱除率可以保持在97.8%以上;当H2S负荷为4.37~4.93kg·m^-3·d^-1时,H2S去除率可达到99%以上,且主要副产物为单质硫.通过增大进气负荷、降低通气量可以获得较高的单质硫回收率.
The air-lift reactor with an effective volume of 0.40 L was used to study the capability of removing H2 S. The bacteria which were used to remove H2 S were isolated and cultured in our lab. Under the conditions of 28 ℃ and initial pH 8, the effects of different gas flows and different H2 S concentrations on the microbial desulfurization capacity and, efficiency of the reactor were investigated. The effects of H2 S input load and gas flows on the forming rate of sulfate were also investigated. The results showed that the optimum gas flow was 0.2 L/min. Under this condition, when the input load of H2S was 5.76 kg·m^-3·d^-1, the maximum elimination capacity was 5.62 kg·m^-3·d^-1, while the removal efficiency could still maintain more than 97. 8%. When the input load was 4.37 -4.93 kg·m^-3·d^-1, the removal efficiency of H2S could reach 99% , and the major product was sulfur. These data indicated that high recovery rate of sulfur can be acquired by increasing the input load of H2 S or decreasing the gas flow.