位置:成果数据库 > 期刊 > 期刊详情页
微波辐射制备聚丙烯酸异丁酯吸油烟树脂及其性能和表征
  • ISSN号:1001-9731
  • 期刊名称:《功能材料》
  • 时间:0
  • 分类:TQ32[化学工程—合成树脂塑料工业]
  • 作者机构:[1]华南理工大学传热强化与过程节能教育部重点实验室,化工纂能源学院,广东广州510640
  • 相关基金:国家自然科学基金资助项目(20576041)
中文摘要:

提出应用微波辐射法制备聚丙烯酸异丁脂吸油烟树脂,采用傅立叶红外光谱仪和扫描电子显微镜对树脂的化学基团、表面形貌和孔结构进行了表征,研究了引发剂用量、交联剂用量、合成反应时间对树脂吸附气相油烟性能的影响。结果表明,随着引发剂和交联剂用量增加,树脂吸油烟率逐渐增大,分别在0.5%和0.15%时候达到最大,此时材料表面形成了较多和较深的孔,其后随着引发剂量和交联剂的增加吸油烟率反而减小。与常规条件下合成的NR树脂相比,微波辐射下合成WR树脂不仅可获得较高的反应转化率、还可缩短一半的反应时间,而且其吸附气相油烟率也高于NR树脂。微波辐射合成的树脂的吸附气相油烟性能还优于普通活性炭。

英文摘要:

In this paper,polyi-butylacrylat resin was synthesized by means of microwave irradiation.Chemical groups,morphologies and textural properties of the synthesized polyi-butylacrylat resins were characterized respectively by using fourier transform infrared spectroscopy(FT-IR) and scanning electron microscopy(SEM).Its adsorption of oil fume was measured.The effects of textural properties of on its adsorption of oil fume were discussed.Results showed that the initiator Dose and cross-linking agent dose had influence on adsorption capacity of the synthesized resins,and when the initiator dose and cross-linking agent dose were respectively 0.5% and 0.15%,the synthesized resins had not only a developed porous structure but also maximum amount adsorbed of oil fume.Henceforth,with increase of the initiator dose and cross-linking agent dose,adsorption capacity of the synthesized resins toward the oil fume decreased.In comparison with synthesis method of traditional water-bath heating,the use of microwave irradiation method can improve efficiency of conversion reaction,and greatly shorten synthesis reaction time from 4h to 2h.The WR resin synthesized by microwave irradiation had higher adsorption capacity of oil fume compared to the NR resin synthesized by traditional water-bath heating method.In addition,the amount adsorbed of oil fume on the WR resin was higher than that on activated carbon.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《功能材料》
  • 北大核心期刊(2011版)
  • 主管单位:重庆材料研究院
  • 主办单位:重庆材料研究院
  • 主编:黄伯云
  • 地址:重庆北碚区蔡家工业园嘉德大道8号
  • 邮编:400707
  • 邮箱:gnclwb@126.com
  • 电话:023-68264739
  • 国际标准刊号:ISSN:1001-9731
  • 国内统一刊号:ISSN:50-1099/TH
  • 邮发代号:78-6
  • 获奖情况:
  • 2008、2011年连续获中国精品科技期刊,2010获重庆市双十佳期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:30166