欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
以5-溴水杨醛和乙胺合成的希夫碱为定向配体,采用溶剂热法,在乙腈溶液中与硝酸钴反应,合成了一个新型的钴（Ⅲ）配合物[Co（HL）3]（1）,HL=5-溴水杨醛缩甲胺希夫碱,其结构经单晶X-射线衍射进行测定,并通过IR对结构进行了表征.配合物1属于单斜晶系,P21/n空间群,晶胞参数a=0.936 93（12）nm,b=2.133 86（19）nm,c=1.457 80（14）nm;β=103.432（11）°;V=2.834 8（5）nm3,Z=4,Dc=1.734g·cm-3,R1=0.080 7,wR2=0.218 7,S=1.03.配合物1中Co（Ⅲ）分别与3个二齿配体上的3个O原子和3个N原子配位,形成轻度扭曲的八面体构型.分子间通过C—H…Br弱作用相互连接形成三维网络结构.
英文摘要：
A new cobalt complex [Co（HL）3] （1）, （HL= 5-Bromo-2-ethyliminomethyl-phenol）, was synthesized by solvothermal method from 3,5-dibromo-2-hydroxy-benzaldehyde, ethylamine and co- balt nitrate. The structure was characterized by IR and XRD. 1 belongs to the monoclinic system, space group P21/n, with a=0.936 93（12）nm,b=2.133 86（19）nm,c=1.457 80（14）nm;β=103.432（11）°;V=2.834 8（5）nm3,Z=4,Dc=1.734g·cm-3,R1=0.080 7,wR2=0.218 7,S=1.03. Each Co（ Ⅲ ） atom is six coordinated by three N and three O from three bidentate ligands HL to give a slightly distorted octahedral geometry. Molecules are extended to 3D network through the C-H…Br hydrogen bonds.
同期刊论文项目
同项目期刊论文
Solvothermal synthesis, crystal structure and magnetic behavior of a Schiff base heterometallic clus
trans-Bis[4-amino-N-(pyrimidin-2-yl- KN)benzenesulfonamidato-jN]bis(N,N- dimethylformamide-KO)cobalt
Synthesis and crystal structures of two heterobinuclear Nickel polymer [NiNaL(dca)]n and [NiNaL(dca)
A novel heterometallic coordinational polymer with 2-[Bis-(2-hydroxy-ethyl)-amino]-ethanesulfonic ac
A Novel Heterometallic Cluster-Based Coordinational Polymer with 2-[Bis-(2-hydroxy-ethyl) -Amino] -E
Solvothermal syntheses and structures of three clusters based on (1H-benzoimidazol-2-yl)-methanethio
Synthesis and Crystal Structure of an Oxo Bridged Disc-like Heptanuclear Co(II) Cluster with Unconve
Synthesis, Structure, and Luminescent Property of One Zinc (II) Coordination Polymer Constructed fro
Room Temperature Syntheses, Structures and Magnetic Properties of Two Heterometallic Tetranuclear Cl
Microwave-assisted Synthesis, Structure, and Properties of a Heptanuclear Cobalt Cluster with 2-Ethy
Synthesis and Crystal Structures of Two Heterobinuclear Nickel Polymers [NiNaL(dca)](n) and [NiNaL(d
Room temperature syntheses, crystal structures and properties of two new heterometallic polymers bas
Structural variation from heterometallic cluster-based 1D chain to heterometallic tetranuclear clust
Ligand induced diversification from tetranuclear to mononuclear compounds: Syntheses, structures and
A Novel Heterometallic Cluster-Based Coordinational Polymer with 2-[Bis-(2-hydroxy-ethyl)-Amino]-Eth
Structural Variation from Heterometallic Heptanuclear, Heptanuclear to Cubane Clusters Based on 2-hy
Microwave-Assisted Synthesis, Structure and Properties of a Nano-Double-Bowl-Like Heptanuclear Nicke
Two disc-like heptanuclear clusters based on Schiff base: syntheses, structure and magnetic properti
Microwave-assisted synthesis, structure and property of a spin-glass heptanuclear nickel cluster wit
Syntheses, structures and properties of three new trinuclear nickel clusters with (2-hydroxy-4-metho
Synthesis Crystal Structures and Properties of Three Complexes of 5-(pyridin-2-ylmethoxy) isophthali
Syntheses, Crystal Structure and Properties of a New Co(II) Coordination Polymer Constructed from 1,
期刊信息
位置：