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Recent progresses of polymer crystallization studied by AFM
  • 时间:0
  • 分类:O782[理学—晶体学]
  • 作者机构:1. State Key Laboratory of Polymer Physics and Chemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100080, China , 2. Graduate School of the Chinese Academy of Sciences, Beijing, 100039, China , 3. Department of Chemical Engineering, Hong Kong University of Science and Technology, Hong Kong, China ,
  • 相关基金:This work was supported by the National Natural Science Foundation of China ; the Hong Kong Government Research Grants Council Joint Research Scheme (Grant Nos. 20131160730 ; NJHKUST 618/01) ; the National Natural Science Foundation of China (Grant N
中文摘要:

The crystallization of polymers has been one of the major topics in polymer physics. Spherulites are common crystalline structures observed in semi-crystalline polymers. Many studies[1-5] have been performed to investigate the detailed structures and formation mechanisms. It is generally accepted that the three-dimensional geometry of spherulites develops from a stack of lamellae. During the growth process, the stacked lamellae splay apart continually and branch occasionally[6.7]. However, there are many unanswered questions. For example, what is a pri-

英文摘要:

We have given a brief overview of our recent studies of polymer crystallization using AFM. We believe that AFM will be a most important tool for investigating the crystalline structure of polymers in the near future. The in situ probing of the following processes, such as crystallization, melting, re-crystallization, etc., will provide us an opportunity to get a better understanding of polymer crystallization processes. The detailed investigation of the morphological changes of semi-crystalline polymers will provide more and more experimental results for the development of the polymer crystallization theory.

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