通过共沉淀法制备一系列含有不同阳离子的层状双金属氢氧化物(m^2+-m^3+-LDHs,m^2+为Zn2+或Mg^2+,m^3+为Fe^3+或Al^3+),采用X射线衍射仪(XRD)、BET、X射线荧光光谱仪(XRF)手段对材料进行了表征,研究了不同阳离子比例、种类和初始pH对LDHs吸附诺氟沙星(NOR)的影响。结果表明,n(m^2+):n(m^3+)=2:1时的LDHs材料对NOR的吸附量最大,且Mg-Al-LDHs的吸附效果最好;LDHs对诺氟沙星的吸附过程符合准2级动力学,吸附过程符合langmiur吸附类型,pH在3-10内吸附量稳定。
M^2+-M^3+-layered double hydroxides(M^2+-M^3+-LDHs) containing M^2+:Zn^2+/Mg^2+; m^3+and Fe^3+/Al^3+were prepared by the co-precipitation method.The solids were characterized by X-ray diffraction(XRD),Brunner-Emmet-Teller(BET) and X-ray fluorescence analysis(XRF).The effects of LDHs with different M^2+/M^3+molar ratios,type and the initial solution pH on norfloxacin(NOR) adsorption were investigated.The results showed that Mg-Al-LDHs with n(M^2+):n(M^3+) of 2:1 exhibited the best performance for NOR adsorption.Two kinetic models were used to fit the experimental data,indicating that the pseudo-second-order kinetics model could better describe the adsorption process.Langmuir model fitted well with the adsorption equilibrium data.The adsorption amount of NOR was stable within initial pH ranging from 3-10.