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Synergistic effects of 4-nitrophenol degradation using gamma irradiation combined with a advanced oxidation process
  • ISSN号:1673-9108
  • 期刊名称:《环境工程学报》
  • 时间:0
  • 分类:X703[环境科学与工程—环境工程] TP212[自动化与计算机技术—控制科学与工程;自动化与计算机技术—检测技术与自动化装置]
  • 作者机构:[1]Department of Hydraulic Engineering, Tsinghua University,Beijing 100084, China, [2]Collaborative Innovation Center for Advanced NuclearEnergy Technology, INET, Tsinghua University,Beijing 100084, China, [3]Beijing Key Laboratory of Radioactive Waste Treatment,INET, Tsinghua University, Beijing 100084, China
  • 相关基金:The study was supported by the Program for Changjiang Scholars and Innovative Research Team in University (No. IRT-13026), the National High Technology Research and Development Program (No. 2009AA063905), the International S&T Cooperation Program (ISTCP) of China (No. 2009DFB90600) and the National Natural Science Foundation of China (No. 51338005).
中文摘要:

The radiation-induced degradation of 4-nitrophenol(4-NP) was performed in combination with a Fenton reagent, H2O2, and Ti O2 nanoparticles to investigate the synergetic effects of radiolytical degradation combined with other advanced oxidation processes. The experimental results indicated that the degradation efficiency of 4-NP was 87.5, 57.4, and 41.0 % at a dose of 20 k Gy when its initial concentration was 100, 200, and 350 mg/L, respectively. Radiation combined with H2O2, the Fenton method,and Ti O2 remarkably increased the degradation efficiency of 4-NP, showing the synergetic effects. Radiation may enhance the biodegradability of 4-NP, suggesting that it has the potential to be used as a pretreatment method in combination with the biological method for the treatment of industrial wastewater containing toxic organic pollutants. Major intermediates during the 4-NP degradation process were identified and a possible degradation pathway was tentatively proposed.

英文摘要:

The radiation-induced degradation of 4-nitro- phenol (4-NP) was performed in combination with a Fen- ton reagent, H202, and TiO2 nanoparticles to investigate the synergetic effects of radiolytical degradation combined with other advanced oxidation processes. The experimental results indicated that the degradation efficiency of 4-NP was 87.5, 57.4, and 41.0 % at a dose of 20 kGy when its initial concentration was 100, 200, and 350 mg/L, respec- tively. Radiation combined with H202, the Fenton method, and TiO2 remarkably increased the degradation efficiency of 4-NP, showing the synergetic effects. Radiation may enhance the biodegradability of 4-NP, suggesting that it has the potential to be used as a pretreatment method in combination with the biological method for the treatment of industrial wastewater containing toxic organic pollu- tants. Major intermediates during the 4-NP degradation process were identified and a possible degradation pathway was tentatively proposed.

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期刊信息
  • 《环境工程学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:曲久辉
  • 地址:北京东黄城根北街16号
  • 邮编:100017
  • 邮箱:
  • 电话:010-62941074
  • 国际标准刊号:ISSN:1673-9108
  • 国内统一刊号:ISSN:11-5591/X
  • 邮发代号:82-448
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘
  • 被引量:20083