位置:成果数据库 > 期刊 > 期刊详情页
二次注射成型聚丙烯中剪切诱导连接界面的形态演变
  • 期刊名称:高分子通报,(11),32-36,2009。
  • 时间:0
  • 分类:TQ320.662[化学工程—合成树脂塑料工业] TP368.32[自动化与计算机技术—计算机系统结构;自动化与计算机技术—计算机科学与技术]
  • 作者机构:[1]高分子材料工程国家重点实验室四川大学高分子研究所,成都610065
  • 相关基金:国家自然科学基金项目(50703027),国家重点基础发展规划项目(2005CB623800)
  • 相关项目:注射连接过程中结晶聚合物及其复合材料的界面形态控制及机理研究
中文摘要:

研究了剪切作用对二次注射成型聚丙烯连接界面形态演变的影响。利用偏光显微镜研究了连接界面距离浇口不同区域和不同位置的形态差异,探索了连接界面形态的演变规律,通过改变注射压力和注射速度对其加以验证,并通过DSC分析证实了形态结构的差异。研究表明:剪切作用对连接界面形态的影响显著,在高剪切作用下分子链沿流动方向取向程度高,不利于其规整排列并沿垂直界面方向生成横晶;可以通过注射压力和注射速度来控制连接界面的剪切作用,从而得到具有完善横晶结构的连接界面形态。

英文摘要:

The effects of shear on interfacial morphology evolution of over-injection molded polypropylene were investigated in this article. The interfacial morphologies at different distance from the gate under different shear effects, induced by different injection pressure and injection speed, was observed by polarized light microscopy (PLM) and differential scanning calorimetry (DSC). It was found that injection pressure played more predominant role in the interracial morphology development than injection speed. The PLM results also showed that less transcrystal was found at the interface due to high injection pressure, indicating that enhanced molecular orientation by increasing injection pressure was unfavorable for the crystallization at the interface during over-injection molding. The interfacial morphology can be controlled by changing injection pressure and injection speed.

同期刊论文项目
同项目期刊论文