在熔炼过程中以单质形式加入Sb,研究了0~1.8%(质量分数,下同)范围内不同含量的Sb对Mg-3Sn-1-5Al-1Zn-1.2Si合金显微组织和力学性能的影响。结果表明,Sb能与Mg基体优先生成Mg3Sb2相,加入1.0%的Sb对Mg2Si相的汉字状结构变质作用显著,Mg2Si中的Si能与Sn发生取代反应,生成富Sn的Mg2(Si,Sn)。随着Sb的增加,铸态合金和挤压态合金的延伸率逐渐减小,而抗拉强度呈现先增加后降低的趋势,塑性和强度的最佳配合点约为1.0%,Sb含量的增加有利于改善Mg-3Sn-1-5Al-1Zn-1.2Si合金的耐热性能。
The effects of Sb on microstructure and mechanical properties of Mg-3Sn-1-5Al-1Zn-1.2Si magnesium alloy were studied when Sb was added into melt in the form of pure metal with the range of 0-1.8% (mass fraction, similarly hereinafter). The results demonstrate that Sb element and Mg matrix preferentially combine to form Mg3Sb2 phases, the addition of 1.0% Sb has a strong modification for Chinese script morphology Mg2Si phases. Sn can replace Si of Mg2Si then form Sn-rich Mg2 (Si,Sn) compound phase, whose physical properties lie between Mg2Si and Mg2Sn. With the increase of Sb content, the elongations of as-cast and extruded alloy decrease, and tensile strengths increase firstly and then decrease, a best combination of strength and plasticity was 1.0% or so. The increase of Sb was beneficial to improve the heat resistance of Mg-3Sn-1-5Al-1Zn-1.2Si alloy.