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Comparative studies on flotation of illite, pyrophyllite and kaolinite with Gemini and conventional cationic surfactants
  • ISSN号:1003-6326
  • 期刊名称:《中国有色金属学报:英文版》
  • 时间:0
  • 分类:TQ423.12[化学工程] TD952.3[矿业工程—选矿]
  • 作者机构:[1]School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China, [2]School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
  • 相关基金:Project(2005CB623701) supported by the National Basic Research Program of China; Project(50874118) supported by the National Natural Science Foundation of China; Projet(2007B52) supported by the Foundation for the Author of National Excellent Doctoral Dissertation of China .
中文摘要:

寻找有效硅酸盐矿物质收集者的一个新奇的班,双子座第四级的铵盐表面活化剂(钢瓶煤气--, -bis(dimethyl dodeculammonium 溴化物), 12-4-12 )并且它的相应常规 monomeric 表面活化剂( dedecyl trimethyl 铵溴化物, DTAB )被采用比较地学习 illite 的筹款行为,叶卉石和 kaolinite 。有双子座表面活化剂的三种硅酸盐矿物质作为收集者揭示比与相应的传统的远好的 floatability。在 pH 6,有 3.5 的 illite,叶卉石和 kaolinite 的最好的恢复

英文摘要:

To search a novel class of effective silicate mineral collectors, the Gemini quaternary ammonium salt surfactant (butane-α, ω-bis(dimethyl dodeculammonium bromide), 12-4-12) and its corresponding conventional monomeric surfactant (dedecyl trimethyl ammonium bromide, DTAB) were adopted to comparatively study the flotation behaviors of illite, pyrophyllite and kaolinite. Three silicate minerals with the Gemini surfactant as collector reveal floatability far better than with the corresponding traditional one. At pH 6, the best recoveries of illite, pyrophyllite and kaolinite with 3.5 × 10 ^-4 mol/L 12-4-12 are 99.2%, 91.7% and 99.6%, respectively The fluorescence and contact angle measurement were also conducted for the further investigation of surfactants aggregation behavior and silicate mineral surface hydrophobic properties. FTIR spectra analysis and electrokinetic analysis show that the mechanism of adsorption of collector molecules on mineral surfaces is almost identical for the electronic attraction and hydrogen bonds effect. The superior collecting power of dimeric collector may be attributed primarily to its special structure and its essential properties.

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期刊信息
  • 《中国有色金属学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国有色金属学会
  • 主编:黄伯云
  • 地址:中国长沙中南大学
  • 邮编:410083
  • 邮箱:f-xsxb@csu.edu.cn
  • 电话:0731-88830949
  • 国际标准刊号:ISSN:1003-6326
  • 国内统一刊号:ISSN:43-1239/TG
  • 邮发代号:42-317
  • 获奖情况:
  • 国家“双百”期刊,第二届全国优秀科技期刊评比二等奖,中国有色金属工业总公司优秀科技期刊一等奖
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  • 被引量:1159