以CH2Cl2为溶剂,通过5-(4-氨基)苯基-10,15,20-三苯基卟啉(MATPP)与硬脂酸直接反应得到一种新型不对称酰胺基卟啉配体5-(4-硬脂酸酰亚胺基)苯基-10,15,20-三苯基卟啉配体(SITPPH2),利用紫外-可见光谱、红外光谱、核磁共振氢谱、质谱、元素分析等测试方法对化合物的结构加以确认。热分析表明,卟啉配体从200℃开始分解,具有较高的热稳定性。
In this paper, an unsymmetrical imide porphyrin ligand, 5- (4-stearicimidephenyl) phenyl- 10, 15, 20-triphenyl porphyrin (SITPPH2) had been synthesized by the reaction of the stearic acid and 5-(4- aminophenyl)- 10, 15, 20-triphenylporphyrin (MATPP) in CH2Cl2. The SITPPH2 was characterized by means of UV-Vis spectra, Mass spectra, elemental analyses, IR spectra and 1H NMR spectra. The thermal studies showed that the porphyrin SITPPH2 could be dried under 200℃ and had higher thermal stability.