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操作参数对生物质热解液化及焦炭特征的影响
  • ISSN号:1672-1292
  • 期刊名称:南京师范大学学报(工程技术版)
  • 时间:0
  • 页码:29-33
  • 分类:X511[环境科学与工程—环境工程]
  • 作者机构:[1]南京师范大学能源与机械工程学院,江苏南京210042
  • 相关基金:国家自然科学基金(50976049); 江苏省自然科学基金(BK2011788)
  • 相关项目:烟气中单质汞的等离子放电协同光催化氧化特性研究
中文摘要:

以稻壳为研究对象,在固定床中热解制取液体生物油.实验研究了热解温度、氮气流速和升温速率对热解3种产物分布的影响.在25℃/min的升温速率达到热解终温550℃,氮气流速为150 mL/min工况下液体产率达到最大值49.91%.随着升温速率的增加液体产率升高,焦炭的产率降低.利用热重分析考察了原料的热分解特性.通过X射线衍射方法和SEM对热解焦炭的晶相和形态进行分析.研究表明热解温度对焦炭的晶相和表面形态的影响很大,在550℃的热解温度下得到的焦炭有较突出孔状结构.

英文摘要:

The experiments of the rice husk pyrolysis were performed in a fixed-bed reactor to produce bio-oil. The effects of the different operation factors such as pyrolysis temperature, sweeping gas ( N2 ) flow rates and heating rates on the yields of three products and the characteristics of bio-char were investigated. The maximum bio-oil yield of 49.91% was obtained at 550~C pyrolysis temperature with a heating rate of 25~C/min and nitrogen flow rate of 150 mL/min. As the heating rate increased, it favored the yields of liquid product, yet the bio-char yields decreased. Thermogravimetric analysis (TGA) was introduced to study the thermal decomposition of the feedstock. Crystals and morphology of bio-char with different pyrolysis temperatures were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis. The results showed that pyrolysis temperatures played an important role on the surface morphology and crystal phase of bio-char and the prominent porosity with the bio-char which was generated under 550%; pyrolysis temper- ature was observed.

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期刊信息
  • 《南京师范大学学报:工程技术版》
  • 主管单位:江苏教育厅
  • 主办单位:南京师范大学
  • 主编:田立新
  • 地址:南京宁海路122号
  • 邮编:210097
  • 邮箱:gkxb@njnu.edu.cn
  • 电话:025-83598631
  • 国际标准刊号:ISSN:1672-1292
  • 国内统一刊号:ISSN:32-1684/T
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国剑桥科学文摘
  • 被引量:2371