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喷涂制备聚合物太阳能电池阳极缓冲层中所用溶液浓度对器件性能影响机理
  • ISSN号：1673-0291
  • 期刊名称：《北京交通大学学报：自然科学版》
  • 时间：0
  • 分类：TM914.1[电气工程—电力电子与电力传动]
  • 作者机构：[1]北京交通大学发光与光信息技术教育部重点实验室,北京100044, [2]北京印刷学院,北京102600
  • 相关基金：国家自然科学基金项目资助（60977027,60825407）; 北京市科委资助项目（Z090803044009001）; 中央高校基本科研业务费专项资金资助项目（2010JBZ003）
作者： 陈征[1], 邓振波[1], 周茂杨[1], 殷月红[1], 杜海亮[1], 邹业[1], 伦建超[1], 王永生[1,2]
关键词： 光电子器件, 聚合物太阳能电池, 喷涂, PEDOT, PSS, optoelectronic device, polymer solar cells, Air-brush, PEDOT：PSS
中文摘要：

以在空气中结构稳定和电导率高等特点的PEDOT：PSS为样本,针对溶液浓度与喷涂薄膜成膜特性及在此基础上制备的P3HT：PCBM体异质结聚合物太阳能电池器件,进行了表征和分析.结果表明：器件的电流密度和效率随喷涂溶液浓度增大而提高的原因是喷涂溶液浓度的增加导致所制得薄膜的表面粗糙度增大,从而增大了与体异质结的接触面积,提高了载流子的传输和收集效率;在采用浓度为66.67%的PEDOT：PSS水溶液喷涂制备的缓冲层基础上制备的P3HT：PCBM体异质结聚合物太阳能电池,短路电流达到12.08mA/cm2.

英文摘要：

A series of P3HT： PCBM bulk heterojunetion polymer solar cell was fabricated with buffer layer which air-brushed from PEDOT：PSS water solution with different concentrationgs. It was found that Higher PEDOT：PSS concentration solution which used to air-brash spray deposition led to higher roughness of the buffer layer, further led to higher photon-generated carrier transporting and gathering efficiency. The short circuit current density of polymer solar cell achieved to 12.08mA/cm2 which with a buffer layer air-brushed from 66.67% concentration of PEDOT：PSS water solution.

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期刊信息
  • 《北京交通大学学报：自然科学版》
  • 北大核心期刊（2011版）
  • 主管单位:教育部
  • 主办单位:北京交通大学
  • 主编：孙守光
  • 地址：北京市西直门外上园村3号北方交通大学8楼8101室
  • 邮编：100044
  • 邮箱：bfxb@bjtu.edu.cn
  • 电话：010-51688053
  • 国际标准刊号：ISSN：1673-0291
  • 国内统一刊号：ISSN：11-5258/U
  • 邮发代号:
  • 获奖情况:
  • 1995年铁道部科技期刊一等奖、1999年教育部组织的...
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  • 被引量:5152