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Spatial and temporal distribution characteristics of synthetic musk in Suzhou Creek
  • ISSN号:1000-6923
  • 期刊名称:《中国环境科学》
  • 时间:0
  • 分类:X522[环境科学与工程—环境工程] TQ654.1[化学工程—精细化工]
  • 作者机构:[1]School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, P. R. China, [2]State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, P. R. China
  • 相关基金:Project supported by the National Natural Science Foundation of China (Grant No.40872204), the National Basic Research Program of China (Grant No.2008CB418200), and the Shanghai Leading Academic Discipline Project (Grant No.S30109) We thank WANG Jun and YAO Yu for their help in sample collection and analysis.
中文摘要:

在苏州溪的七合成麝香的污染层次和分布在这研究被调查。二多不的麝香, 1 , 3 , 4 , 6 , 7 , 8-hexahydro-4 , 6 , 6 , 7 , 8 , 8-hexamethylcyclopenta (g) -2-benzopyran ( HHCB )和 7-acetyl-1 , 1 , 1 , 3 , 4 , 4 , 6-hexamethyl-1 , 2 , 3 , 4-tetrahydronaphthalene ( AHTN ),在所有样品被发现。HHCB 和 AHTN 的范围从 8 ng/L 到 138 ng/L 并且从 1 ng/L,并且从 2 ng/g 到表面水里的 25 ng/L 到 77 ng/g (干燥重量) 并且从 1 ng/g 到 31 ng/g (干燥重量) 在沉积分别地。HHCB 和 AHTN 的全部的集中在表面水里显示出明显的空间变化:上面的活动范围(郊区) 13 不到更低的功课(城市的区域) ;并且在沉积,麝香层次在城市的区域也是更高的。也 seasonaly 显示出的分发模式在表面水和沉积里两个都改变了特征。分发系数(Kp ) 和标准化分发系数(Koc ) 通过麝香集中和 octanol 水分区系数(Kow ) 被计算。结果证明 AHTN 更容易被专心于沉积。麝香的吸附与在苏州溪增加全部的器官的碳(TOC ) 被增加。HHCB 和 AHTN 的重要积极关联在这研究被发现,它显示了一样的污染来源:香料物质的使用和分泌物。

英文摘要:

Contamination levels and distribution of seven synthetic musks in Suzhou Creek were investigated in this study. Two polycyclic musks, 1, 3, 4, 6, 7, 8-hexahydro-4, 6, 6, 7, 8, 8-hexamethylcyclopenta(g)-2-benzopyran (HHCB) and 7-acetyl-1, 1, 1, 3, 4, 4, 6-hexamethyl-1, 2, 3, 4-tetrahydronaphthalene (AHTN), were found in all samples. The ranges of HHCB and AHTN were from 8 ng/L to 138 ng/L and from 1 ng/L to 25 ng/L in surface waters, and from 2 ng/g to 77 ng/g (dry weight) and from 1 ng/g to 31 ng/g (dry weight) in sediments respectively. The total concentration of HHCB and AHTN showed obvious spatial change in surface waters: the upper reaches (suburb) 13 less than the lower course (urban area); and in sediments, the musk levels were also higher in urban area. The distribution pattern also showed seasonaly varied characteristics both in surface waters and sediments. The distribution coefficient (Kp) and standardized distribution coefficient (Koc) were calculated through musk concentrations and octanol-water partition coefficient (Kow). The results showed that AHTN was more easily absorbed in sediments. The adsorption of musk was increased with the increasing of total organic carbon (TOC) in Suzhou Creek. The significant positive correlation of HHCB and AHTN was found in this study, which indicated the same pollution source: the use and discharge of flavoring substances.

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期刊信息
  • 《中国环境科学》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国环境科学学会
  • 主编:王文兴
  • 地址:北京市海淀区红联南村54号
  • 邮编:100082
  • 邮箱:zghjkx1981@126.com
  • 电话:010-62215145
  • 国际标准刊号:ISSN:1000-6923
  • 国内统一刊号:ISSN:11-2201/X
  • 邮发代号:2-572
  • 获奖情况:
  • 国家期刊提名奖,国家“双效”期刊,第三届中国科协优秀科技期刊一等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,英国科学文摘数据库,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:47702