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碳、碳化硅及氮化硅等纳米功能材料的制备
  • ISSN号：1001-9731
  • 期刊名称：《功能材料》
  • 时间：0
  • 分类：O612.4[理学—无机化学;理学—化学] O613.72[理学—无机化学;理学—化学]
  • 作者机构：[1]中国科学技术大学化学与材料科学学院,合肥230026, [2]合肥工业大学化学工程学院,合肥230009
  • 相关基金：国家自然科学基金（No.20431020）资助项目.
作者： 钱逸泰[1,2]
关键词： 碳纳米纤维, 溶剂热法, 催化剂, carbon nanofibers, solvothermal, catalyst
中文摘要：

利用四氢呋喃为溶剂和碳源，通过溶剂热催化方法存500℃一步合成了纳米碳纤维．X-射线衍射（XRD）分析显示此法合成的碳纤维晶型为碳的六方石墨相，场发射电镜（FESEM）和透射电镜（TEM）照片进一步表明碳纤维平均直径为100nm，长度达几百纳米至几微米，高分辨电镜照片揭示产品中碳的品间距为0．34nm；产品纯度通过热重法（TGA）分析；同时，拉曼光谱图显示在1347和1584cm^-1处有2个强峰，这与石墨相碳的典型拉曼光谱图是一致的。

英文摘要：

Carbon nanofibers have been synthesized through a one-pot catalytic solvothermal approach using tetrahydrofuran as the solvent and carbon source at 500 ℃. XRD patterns show that the as-prepared carbon nanofibers are of hexagonal graphite. Field-emission scanning electron microscopy（FESEM） and TEM images indicate that the carbon nanofibers have an average diameter of 100 nm and length ranging from hundreds of nanometers to several micrometers. High-resolution transmission electron microscopy （HRTEM） images reveal that the products consist of graphite layers with interlayer spacing of about 0.34 nm. The purity of the carbon nanofibers is also examined by thermal gravimetric analysis （TGA）. The Raman spectrum has two strong peaks at 1 347 and 1 584 cm^-1, corresponding to the typical Raman peaks of graphitized carbon nanofibers.

同期刊论文项目
有机体系中非氧化物功能材料制备及形成机理
期刊论文 194 会议论文 1 著作 2
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期刊信息
  • 《功能材料》
  • 北大核心期刊（2011版）
  • 主管单位:重庆材料研究院
  • 主办单位:重庆材料研究院
  • 主编：黄伯云
  • 地址：重庆北碚区蔡家工业园嘉德大道8号
  • 邮编：400707
  • 邮箱：gnclwb@126.com
  • 电话：023-68264739
  • 国际标准刊号：ISSN：1001-9731
  • 国内统一刊号：ISSN：50-1099/TH
  • 邮发代号:78-6
  • 获奖情况:
  • 2008、2011年连续获中国精品科技期刊,2010获重庆市双十佳期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:30166