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Non-monotonic influence of a magnetic field on the electrochemical behavior of Fe78Si9B13 glassy alloy in NaOH and NaCl solutions
  • 分类:TG139.8[金属学及工艺—合金;一般工业技术—材料科学与工程;金属学及工艺—金属学] X773[环境科学与工程—环境工程]
  • 作者机构:[1]Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, China, [2]Qingdao Yunlu Energy Technology Co. Ltd., Qingdao 266109, China, [3]School of Mechanical and Electrical Engineering, Weifang University, Weifang 261061, China
  • 相关基金:This work was financially supported by the National Natural Science Foundation of China (No. 51171091), the Excellent Youth Project of Shandong Natural Science Foundation (No. JQ201012), and the Major State Basic Research Development Program of China (No. 2012CB825702).
中文摘要:

The corrosion behavior and microstructure of Fe78Si9B13 glassy alloy in NaOH and NaCl solutions under a 0.02-T magnetic field were investigated through electrochemical testing and scanning electron microscopy(SEM). The current-density prepeak(PP) in the anodic polarization curves in low-concentration NaOH solutions(classified as type I) tends to disappear when the NaOH concentration is increased to 0.4 mol/L and the magnetic field is applied. Under the magnetic field, the height of the second current-density peak is increased in low-concentration NaOH solutions(type I) but decreased in high-concentration NaOH solutions(type II). The non-monotonic effect of the magnetic field was similarly observed in the case of polarization curves of samples measured in NaCl solutions. Ring-like corroded patterns and round pits are easily formed under the magnetic field in NaOH and NaCl solutions. These experimental results were discussed in terms of the magnetohydrodynamic(MHD) effect.

英文摘要:

The corrosion behavior and microstructure of Fe78Si9B13 glassy alloy in NaOH and NaCl solutions under a 0.02-T magnetic field were investigated through electrochemical testing and scanning electron microscopy (SEM). The current-density prepeak (PP) in the anodic polarization curves in low-concentration NaOH solutions (classified as type I) tends to disappear when the NaOH concentration is increased to 0.4 mol/L and the magnetic field is applied. Under the magnetic field, the height of the second current-density peak is increased in low-concentration NaOH solutions (type I) but decreased in high-concentration NaOH solutions (type Ⅱ). The non-monotonic effect of the magnetic field was similarly observed in the case of polarization curves of samples measured in NaCl solutions, Ring-like corroded patterns and round pits are easily formed under the magnetic field in NaOH and NaC1 solutions. These experimental results were discussed in terms of the magnetohydrodynamic (MHD) effect.

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