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脉冲激光法连续制备高蓝光荧光性的修饰纳米ZnO乙醇溶胶
  • ISSN号:0251-0790
  • 期刊名称:《高等学校化学学报》
  • 时间:0
  • 分类:O644.17[理学—物理化学;理学—化学]
  • 作者机构:[1]福建师范大学化学与材料学院高分子研究所,福州350007
  • 相关基金:国家自然科学基金(批准号:50272014);福建省自然科学基金重大项目(批准号:2001F005)和福建省纳米重大专项基金(批准号:2005HZ01-5)资助.
中文摘要:

采用聚焦脉冲激光束轰击浸于含有水杨酸的无水乙醇流动相中的ZnO固体靶,连续制备得到了强度高达1.12×10^5的蓝色荧光(440nm)的水杨酸修饰纳米ZnO乙醇溶胶.考察了修饰剂的种类、浓度、添加顺序和流动相流速对其荧光性能的影响.透射电镜结果表明,所制备的纳米ZnO粒径分布在15~30nm.

英文摘要:

Decorated nano-ZnO ethanol sols which were modified in situ were successively produced by pulsed laser ablation at the interface of ZnO target submerged in the flowing liquid which contained modification agents. It is found that ZnO ethanol sol decorated by Hsal radiates intense blue light under ultraviolet radiation and has a broad emission band centered at 440 nm in the emission fluorescence spectrum. The emission intensity in 440 nm is as high as 1.12 × 105. We studied some factors including different modification agents and their added methods, concentration of Hsal (salicylic acid), flowing liquid velocity, aging time after preparation which have effect on luminescence characteristics of sols. The results shows that the decorated nano-ZnO ethanol sol with best fluorescent characteristics can be obtained in following conditions: ethanol solution of Hsal as flowing liquid, concentration of Hsal is 4.2 × 10 -3 moL/L, flowing liquid velocity is 0. 025 mL/s and proper aging time after preparation the ZnO ethanol sol. TEM results show that the diameter of nano-ZnO particles is about 15—30 nm. The study presents a convenient method to obtain the decorated nano-zinc oxide organic sol of high blue luminescence.

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编:周其凤
  • 地址:吉林大学南胡校区
  • 邮编:130012
  • 邮箱:cjcu@jlu.edu.cn
  • 电话:0431-88499216
  • 国际标准刊号:ISSN:0251-0790
  • 国内统一刊号:ISSN:22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:50676