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中文摘要：
为获得适中乙烯基含量的液体聚丁二烯为目的，对Co（naph）2-Al2（C2H5）3Cl3-P（OPh）3，催化体系进行了较为系统的研究，考察了该体系的催化剂配比、浓度及供电子试剂对分子量、微观结构和转化率的影响．实验结果表明，该体系在一定的条件下可以制备出分子量在700—3500、1，2结构含量在35％-40％且转化率高于55％的液体聚丁二烯．
英文摘要：
Liquid polybutadiene with desirable 1,2-units content was synthesized by Co（naph） 2- Al2（C2H5）3Cl3-P（OPh）3 catalyst system. It was shown that liquid polybutadiene having adequate 1,2-unit content （ vinyl = 35 % -40% ）, molecular weight （Mn = 700-3500）, and acceptabele conversion （ ≥ 55 % ） can synthesized after optimizing polymerization conditions.
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