针对北京地区冬季和春季PM2.5污染特征进行研究.于2009年12月~2010年5月在城市点采集24h大气颗粒物样品,进行颗粒物主要化学组分分析.冬季和春季颗粒物的平均质量浓度分别为(84.97±68.98)μg/m3和(65.25±45.76)μg/m3.冬季和春季颗粒物中二次组分(SNA+SOA)有重要贡献,二次组分分别占颗粒物质量浓度的49%和47%.冬春季重污染时期较强的源排放和低温、低风速、高相对湿度等不利的气象特征使得颗粒物中二次无机离子SNA(NH4+、NO3.、SO42.)的比重较干净天明显上升,其中硝酸盐贡献的增强最为显著.同时冬春季有机物中二次有机组分贡献显著.而受一次源的影响,冬春季重污染时期一次有机物的增强.
A comprehensive measurement was conducted to investigate thecharacteristics of particulate matter (PM)pollution in winter and spring of Beijing. 24-hour particle samples were collected from December to May, 2009~2010,and the chemical compositions of PM2.5 were analyzed. The average PM2.5 massconcentrations were (84.97±68.98)μg/m3and (65.25±45.76) μg/m3 in winter and spring, respectively. Secondary inorganic aerosols, i.e. sulfate, nitrate,andammonium (SNA), and secondary organic aerosols (SOA) were dominant theparticulate matter, with the total fraction(SNA+SOA) of 49% and 47% in winter and spring, respectively. Due to the largesource emissionand unfavorablemeteorological conditions such as low temperature, low wind speed, and high relative humidity; the contributions ofsecondary inorganic aerosols (NH4+、NO3-、SO42-) were enhanced during thepolluted days, and the nitratewas moreenhanced on polluted days. The SOA was always the most importantorganic aerosolcomponentcontributedto PM2.5 inwinter and spring. The contribution ofprimary organicaerosolsalso increased due tothe stagnant meteorological conditionon polluted days.