中文摘要：

以二茂铁为原料,通过合成1,1＇-二乙酰基二茂铁、1,1＇-二茂铁二甲酸、1,1＇-二茂铁二甲酰氯,在高度稀释条件下与4种二羟乙基苯胺进行酯化反应得到了1,9-二羰基-2,8-二氧-5-（4-氟）苯基氮[9]二茂铁酯环蕃a,1,9-二羰基-2,8-二氧-5-（4-甲基）苯基氮[9]二茂铁酯环蕃b,1,9-二羰基-2,8-二氧-5-（4-甲氧基）苯基氮[9]二茂铁酯环蕃c,1,9-二羰基-2,8-二氧-5-（4-硝基）苯基氮[9]二茂铁酯环蕃d.用UV、1HNMR、FT-IR、元素分析和基质辅助激光解析电离-飞行时间质谱（MALDI-TOF）对这些化合物进行了表征.培养了二茂铁酯环蕃a的单晶,并对其结构进行了解析.

英文摘要：

Four novel circlet ferrocenophanes： 1,9-dicarbonyl-2,8-dioxo-5-（4-fluoro）phenyl-N-[9] ester ferrocenophane a, 1,9-dicarbonyl-2,8-dioxo-5-（4-methyl）phenyl-N-[9] ester ferrocenophane b, 1,9-dicarbonyl-2,8-dioxo-5-（4-methoxy）phenyl-N-[9] ester ferrocenophane c, 1,9-dicarbonyl-2,8-dioxo-5-（4-nitro）phenyl- N-[9] ester ferrocenophane d were synthesized starting from ferrocene via 1,1＇-diacetylferrocene, 1,1＇- ferrocene-dicarboxylic acid, 1,1＇-ferrocene-di（carbonyl chloride） with dihydroxyethyl aniline under high dilute condition. The ester ferrocenophanes were characterized by UV, 1H NMR, IR, elemental analysis and matrix assisted laser desorption/ionization-time of flight （MALDI-TOF） MS. The crystals of ester ferrocenophane a were obtained and the crystal structure was determined by X-ray diffraction.