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不同温度烧制介孔碳作为直接甲醇燃料电池催化剂载体
  • 期刊名称:物理化学学报
  • 时间:0
  • 页码:1881-1885
  • 语言:中文
  • 分类:O643[理学—物理化学;理学—化学]
  • 作者机构:[1]上海电力学院能源与环境工程学院,上海200090
  • 相关基金:国家自然科学基金项目(20873031),上海市教委科技创新重点项目(10ZZ116),上海市科委能力建设项目(09230501400,10160502300)和上海市人才发展基金资助
  • 相关项目:含钯高效电催化材料及其表面光谱电化学研究
中文摘要:

以嵌段共聚物P123为模板制备介孔氧化硅SBA-15,并以此SBA-15为模板,以蔗糖为碳源在不同的温度下(600-900℃)制备介孔碳CMK-3.采用浸渍还原法,以硼氢化钠为还原剂,制备介孔碳载Pt电催化剂。即20%(w)Pt/CMK-3.利用循环伏安法(CV)、计时电流法等测试电催化剂对甲醇的催化氧化性能及稳定性.预吸附单层CO溶出伏安法研究测试催化剂抗CO中毒能力.结果表明在烧制温度为900℃时制备的介孔碳载Pt催化剂具有最好的催化性能和稳定性,而在烧制温度为700℃时制各的介孔碳载Pt催化剂对CO有较低的溶出电位.

英文摘要:

Using mesoporous SiO2 (SBA-15) as templates and sugar as a carbon precursor, mesoporous carbon (CMK-3) was prepared at different temperatures (600-900 ℃). 20% (w) Pt/CMK-3 was then prepared by impregnation reduction with sodium borohydride as a reductant. Cyclic voltammetry (CV) and chronoamperometry were applied to study the catalytic performance and stability toward methanol oxidation for the as-prepared catalyst. CO striping voltammetry was used to determine its anti-poisoning capability toward CO. The results show that the PUCMK-3 prepared at 900 ℃ had the best catalytic performance and stability toward methanol but at a carbonization temperature of 700 ℃ the Pt catalyst had a lower stripping potential to CO.

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