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三种污泥水解酸化反应动力学研究
  • ISSN号:1009-2455
  • 期刊名称:《工业用水与废水》
  • 时间:0
  • 分类:X703.1[环境科学与工程—环境工程]
  • 作者机构:[1]安徽建筑大学环境与能源工程学院,合肥230022
  • 相关基金:国家自然科学基金资助项目(51278002)
中文摘要:

通过对絮凝吸附污泥、初沉污泥、剩余污泥水解过程的试验研究,得到其水解过程中SCODCr值随时间的变化规律,发现絮凝污泥水解效果最好,初沉污泥次之,剩余污泥最差。根据试验数据,利用经典的Eastman模式对3种污泥水解酸化动力学模式进行研究,确定了水解反应的关键参数——水解速率常数kh的取值。3种污泥中颗粒性CODCr水解过程均遵循一级动力学方程,模型与试验数据拟合较好。由动力学分析亦可看出在水解反应初期的8 h内kh已高于0.1 d^-1,而反应初期24 h内也比总反应7 d的kh高出4倍,说明水解反应在初期的6-8h已达到较高速率,而后期速率逐渐降低,这就为工程中设计水解池的水力停留时间提供参考。

英文摘要:

Through the experimental study on the hydrolytic process of flocculation adsorption sludge, primary sludge and excess sludge, the change law of SCODCrvalue was observed, and the hydrolysis effect of the flocculation adsorption sludge was found to be the best, followed by primary sludge and excess sludge. According to the experimental data, classic Eastman mode was used to study the kinetics of hydrolytic acidification of the above three kinds of sludge, and then, the key parameters and hydrolysis rate constant khwere determined. The results showed that, the hydrolysis process of particulate CODCrof the mentioned kinds of sludge all followed first-order kinetic equation, and the mathematical model fitted the experimental data well. From the kinetics analysis, it also could be seen that, within the initial 8 hours of the hydrolysis reaction, the khhad been higher than 0.1 d^-1already, and the khof 24 h was 4 times higher than that of 7 d, which indicated that, hydrolytic reaction had reached a higher rate in the early 6-8 h, and the rate in the late stage reduced gradually. The study results provided reference for HRT design of hydrolysis tank in engineering.

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期刊信息
  • 《工业用水与废水》
  • 中国科技核心期刊
  • 主管单位:东华工程科技股份有限公司
  • 主办单位:东华工程科技股份有限公司
  • 主编:马强
  • 地址:安徽省合肥市望江东路70号
  • 邮编:230024
  • 邮箱:cniww@vip.163.com
  • 电话:0551-63626465 63621791
  • 国际标准刊号:ISSN:1009-2455
  • 国内统一刊号:ISSN:34-1204/TQ
  • 邮发代号:26-159
  • 获奖情况:
  • 全国石油和化工优秀期刊一等奖,安徽省优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国剑桥科学文摘,中国中国科技核心期刊
  • 被引量:9410