CO和CO2是反映油纸绝缘系统绝缘故障的重要特征气体。为了研究并比较不同绝缘组合下油中CO和CO2体积分数φ(CO)、φ(CO2)的变化规律,对^#25变压器油、普通纤维素绝缘纸、BIOTEMP植物绝缘油、Munksjo热稳定纸组成的4种油纸复合绝缘在不同温度下进行约4000h的加速热老化试验,对不同油纸复合绝缘的油中CO、CO2体积分数φ(CO)、φ(CO2)及比值φ(CO2)/φ(CO)随老化时间、绝缘纸聚合度的变化规律进行了研究。结果表明:采用Munksjo热稳定纸的油纸复合绝缘时,进入老化初期(聚合度约830)后,φ(CO2)/φ(CO)可以反映绝缘纸老化程度的变化;采用普通纤维素绝缘纸的油纸复合绝缘时,推荐用进入老化中期(聚合度约600)后的φ(CO2)/φ(CO)来量度老化程度的变化;绝缘纸聚合度与φ(CO2)/φ(CO)变化的关系中,影响φ(CO2)/φ(CO)达到最大值及到达时间的主要因素是纸的类型,而油的类型影响较小;与^#25变压器油进行组合时,若用新型Munksjo热稳定纸替换普通纤维素绝缘纸来提高性能,则现行的用φ(CO2)/φ(CO)判断绝缘系统故障信息的标准需要进行适当调整。
CO and CO2 are important gases able to reflect insulating problems of oil-paper insulation. In order to research the changing regularities of volume about CO(φ(CO) ) and CO2(φCO2 ) ) , in oil with different insulation compositions, in this paper, four types of oil-paper insulation compositions, which are composed of kraft paper and thermal upgraded transformer paper named Munksjo and ^# 25 mineral oil, Biotemp vegetable oil, are thermally aged for 4000 hours at different temperature respectively. Then the variations of φ(CO2)/φ( CO) and φ(CO), φ(CO2) dissolved in oil of those compounds are analyzed. The main conclusions obtained from test results are as follows. The φ(CO2 )/φ(CO) can reflect the aging extent of the oil paper compounds containing the thermal upgraded paper when these oil-papers were degraded to their early aging stage (the degree of polymerization of paper is less than 830). It is recommended that the value of φ(CO2 )/φ(CO) should be used to reflect the aging extent of the oil-paper compounds containing regular paper when these oil-papers were degraded to their middle aging stage (degree of polymerization of paper〈600). Among the factors influencing the relation between Dp and φ(CO2)/φ( CO) , the most important one that impacts φ(CO2)/φ(CO) on its maximum value and the time arriving at was the type of paper, the type of oil had a little role on them. The current standard using φ(CO2 )/φ(CO) to evaluate the aging state of oil paper insulation should be revised reasonably, when the thermal upgraded paper was used to improve the anti-aging performances of the regular oil and paper insulation system.